10. A sample of diethyl ether is allowed to stand, over time it reacts with molecular oxygen to form peroxides: OOH O2 and hv R. Propose an arrow-pushing mechanism to illustrate the formation of the peroxide from the ether starting material. Use "R•" as the initiator. Show all curved arrows and single electrons. All steps MUST be propagation steps.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
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Chapter18: Ethers And Epoxides; Thiols And Sulfides
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Problem 59GP: Meerwein's reagent, triethyloxonium tetrafluoroborate, is a powerful ethylating agent that converts...
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10. A sample of diethyl ether is allowed to stand, over time it reacts with molecular oxygen to
form peroxides:
OOH
O2 and hv
Ho Ledn .
Propose an arrow-pushing mechanism to illustrate the formation of the peroxide from the
ether starting material. Use “R•" as the initiator. Show all curved arrows and single electrons.
All steps MUST be propagation steps.
le orle O bra 8 A cetulounle not mmot sonsnoest paiudninoo 1orflo eno ebivo19
Todid odt elolo 20utoule owl erti neewledzwog bayuo pnieu Inemavem.aortoeln
mot eonanaeor gniludhino0
eo complete curved emow mechenieis that
In the reaclin,
the
chow
HBr
HO
Transcribed Image Text:10. A sample of diethyl ether is allowed to stand, over time it reacts with molecular oxygen to form peroxides: OOH O2 and hv Ho Ledn . Propose an arrow-pushing mechanism to illustrate the formation of the peroxide from the ether starting material. Use “R•" as the initiator. Show all curved arrows and single electrons. All steps MUST be propagation steps. le orle O bra 8 A cetulounle not mmot sonsnoest paiudninoo 1orflo eno ebivo19 Todid odt elolo 20utoule owl erti neewledzwog bayuo pnieu Inemavem.aortoeln mot eonanaeor gniludhino0 eo complete curved emow mechenieis that In the reaclin, the chow HBr HO
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