11. two moles of ethyl phenylacetate undergo condensation to give a beta-keto ester. 12. a trimyristin undergoes hydrogenolysis 13. p-nitroaniline reacts with NaNO₂/HCI at 0°C

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter23: Addition To A Carbonyl
Section: Chapter Questions
Problem 25E
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Hello! I already have answers in numbers 11 to 14 but please answer them for me to check if my answer is correct. Please answer numbers 11 to 14. Thank you very much.

1. Draw the structure of the organic product/s when:
1. propanal reacts with ammoniacal AgNO, (Tollens' reagent)
2. 3-methylbutanal forms a cyanohydrin
3. 4-methyl-2-pentanone reacts with Grignard reagent, CH3CH₂MgBr
4. 2-methylhexanal reacts with 2 moles of ethanol in dry acid
5. two moles of phenylacetaldehyde undergo condensation to give an aldol
6. the product of no.5 undergoes dehydration
7.
D-arabinose reacts with dilute nitric acid with heating
8. benzoic acid reacts with excess isopropyl alcohol and acid catalyst
9. propanoic anhydride reacts with ammonia
10. ethyl benzoate undergoes acid catalyzed hydrolysis
11. two moles of ethyl phenylacetate undergo condensation to give a beta-keto ester.
12. a trimyristin undergoes hydrogenolysis
13. p-nitroaniline reacts with NaNO₂/HCI at 0°C
14. product of no. 13 reacts with CuCN/KCN
HO
-H
-OH
-OH
CH₂OH
D-arabinose
H-
H
-CH₂-C-H
phenylacetaldehyde
11
H₂C-O-C
O
11
HC-0-C.
L i
H₂C-O-C.
-CH₂-C-OCH₂CH3
ethyl phenylacetate
trimyristin
Transcribed Image Text:1. Draw the structure of the organic product/s when: 1. propanal reacts with ammoniacal AgNO, (Tollens' reagent) 2. 3-methylbutanal forms a cyanohydrin 3. 4-methyl-2-pentanone reacts with Grignard reagent, CH3CH₂MgBr 4. 2-methylhexanal reacts with 2 moles of ethanol in dry acid 5. two moles of phenylacetaldehyde undergo condensation to give an aldol 6. the product of no.5 undergoes dehydration 7. D-arabinose reacts with dilute nitric acid with heating 8. benzoic acid reacts with excess isopropyl alcohol and acid catalyst 9. propanoic anhydride reacts with ammonia 10. ethyl benzoate undergoes acid catalyzed hydrolysis 11. two moles of ethyl phenylacetate undergo condensation to give a beta-keto ester. 12. a trimyristin undergoes hydrogenolysis 13. p-nitroaniline reacts with NaNO₂/HCI at 0°C 14. product of no. 13 reacts with CuCN/KCN HO -H -OH -OH CH₂OH D-arabinose H- H -CH₂-C-H phenylacetaldehyde 11 H₂C-O-C O 11 HC-0-C. L i H₂C-O-C. -CH₂-C-OCH₂CH3 ethyl phenylacetate trimyristin
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