1,2 diols form carbonyl compounds via the Pinacol Rearrangement. Propose a stepwise mechanism for Map this reaction. Details count; include all nonbonding electrons and formal charges! Draw intermediate structure; add curved arrows. Omit H20. Draw intermediate structure; add curved arrows. Omit H2O. Add curved arrows. ӧн, Н loss of H20 :он Draw intermediate structure; add curved arrows. Omit H20. Draw intermediate structure; add curved arrows. loss of H* (as H30*) н 1L
1,2 diols form carbonyl compounds via the Pinacol Rearrangement. Propose a stepwise mechanism for Map this reaction. Details count; include all nonbonding electrons and formal charges! Draw intermediate structure; add curved arrows. Omit H20. Draw intermediate structure; add curved arrows. Omit H2O. Add curved arrows. ӧн, Н loss of H20 :он Draw intermediate structure; add curved arrows. Omit H20. Draw intermediate structure; add curved arrows. loss of H* (as H30*) н 1L
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter26: Aldol And Claisen Reactions
Section: Chapter Questions
Problem 26E
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