1,2 diols form carbonyl compounds via the Pinacol Rearrangement. Propose a stepwise mechanism for Map this reaction. Details count; include all nonbonding electrons and formal charges! Draw intermediate structure; add curved arrows. Omit H20. Draw intermediate structure; add curved arrows. Omit H2O. Add curved arrows. ӧн, Н loss of H20 :он Draw intermediate structure; add curved arrows. Omit H20. Draw intermediate structure; add curved arrows. loss of H* (as H30*) н 1L

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter26: Aldol And Claisen Reactions
Section: Chapter Questions
Problem 26E
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1,2 diols form carbonyl compounds via the Pinacol Rearrangement. Propose a stepwise mechanism for Map
this reaction. Details count; include all nonbonding electrons and formal charges!
Draw intermediate structure;
add curved arrows. Omit H20.
Draw intermediate structure;
add curved arrows. Omit H2O.
Add curved arrows.
ӧн,
Н
loss of
H20
:он
Draw intermediate structure;
add curved arrows. Omit H20.
Draw intermediate structure;
add curved arrows.
loss of H*
(as H30*)
н
1L
Transcribed Image Text:1,2 diols form carbonyl compounds via the Pinacol Rearrangement. Propose a stepwise mechanism for Map this reaction. Details count; include all nonbonding electrons and formal charges! Draw intermediate structure; add curved arrows. Omit H20. Draw intermediate structure; add curved arrows. Omit H2O. Add curved arrows. ӧн, Н loss of H20 :он Draw intermediate structure; add curved arrows. Omit H20. Draw intermediate structure; add curved arrows. loss of H* (as H30*) н 1L
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