13.40 Identify the indicated sets of protons as unrelated, homotopic, enantiotopic, or diastereotopic: (a) (b) н он (c) H CI HH HH HH H H

Macroscale and Microscale Organic Experiments
7th Edition
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
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Chapter13: Mass Spectrometry
Section: Chapter Questions
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13.55 Propose structures for compounds that fit the following 'H NMR data:
(a) C4H,Cl2
2.18 8 (3 H, singlet)
(b) C10H14
1.30 8 (9 H, singlet)
7.30 8 (5 H, singlet)
4.16 8 (2 H, doublet, J = 7 Hz)
5.71 8 (1 H, triplet, J = 7 Hz)
(c) C4H;BrO
2.11 8 (3 H, singlet)
3.52 8 (2 H, triplet, / = 6 Hz)
4.40 8 (2 H, triplet, / = 6 Hz)
(d) C9H11B
2.15 8 (2 H, quintet, J = 7 Hz)
2.75 8 (2 H, triplet, J = 7 Hz)
3.38 8 (2 H, triplet, J = 7 Hz)
7.22 8 (5 H, singlet)
%3D
Transcribed Image Text:13.55 Propose structures for compounds that fit the following 'H NMR data: (a) C4H,Cl2 2.18 8 (3 H, singlet) (b) C10H14 1.30 8 (9 H, singlet) 7.30 8 (5 H, singlet) 4.16 8 (2 H, doublet, J = 7 Hz) 5.71 8 (1 H, triplet, J = 7 Hz) (c) C4H;BrO 2.11 8 (3 H, singlet) 3.52 8 (2 H, triplet, / = 6 Hz) 4.40 8 (2 H, triplet, / = 6 Hz) (d) C9H11B 2.15 8 (2 H, quintet, J = 7 Hz) 2.75 8 (2 H, triplet, J = 7 Hz) 3.38 8 (2 H, triplet, J = 7 Hz) 7.22 8 (5 H, singlet) %3D
13.40 Identify the indicated sets of protons as unrelated, homotopic, enantiotopic,
or diastereotopic:
(a)
(b)
н он
(c)
H CI
H H
H H
HHHH
Transcribed Image Text:13.40 Identify the indicated sets of protons as unrelated, homotopic, enantiotopic, or diastereotopic: (a) (b) н он (c) H CI H H H H HHHH
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