14. Given the 2 reactions below: 2NOE I. 2NO + 0z8) II. 2Li,Og + 1192 KJ → 4Lig Which statement is correct? a) reaction I- endothermic; reaction II– exothermic b) reaction I- heat energy is released; reaction II – heat energy is absorbed c) reaction I - AH sign is positive; reaction II - AH sign is negative d) all of the above + 113KJ + O:(g)

14. Given the 2 reactions below: 2NOE I. 2NO + 0z8) II. 2Li,Og + 1192 KJ → 4Lig Which statement is correct? a) reaction I- endothermic; reaction II– exothermic b) reaction I- heat energy is released; reaction II – heat energy is absorbed c) reaction I - AH sign is positive; reaction II - AH sign is negative d) all of the above + 113KJ + O:(g)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter6: Thermochemistry

Section: Chapter Questions

Problem 46E: The reaction SO3(g)+H2O(l)H2SO4(aq) is the last step in the commercial production of sulfuric acid....

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10.101 Fluorine reacts with liquid water to form gaseous hydrogen fluoride and oxygen. (a) Write a balanced chemical equation for this reaction. (b) Use tabulated data to determine the free energy change for the reaction and comment on its spontaneity. (c) Use tabulated data to calculate the enthalpy change of the reaction. (d) Determine how much heat flows and in what direction when 34.5 g of fluorine gas is bubbled through excess water.
9.83 A student performing a calorimetry experiment combined 100.0 mL of 0.50 M HCl and 100.0 mL of 0.50 M NaOH in a coffee cup calorimeter. Both solutions were initially at 20.0°C, but when the two were mixed, the temperature rose to 23.2°C. (a) Suppose the experiment is repeated in the same calorimeter but this time using 200 mL of 0.50 M HCl and 200.0 mL of 0.50 M NaOH. Will the T observed he greater than, less than, or equal to that in the first experiment, and why? (b) Suppose that the experiment is repeated once again in the same calorimeter, this time using 100 mL of 1.00 M HCl and 100.0 mL of 1.00 M NaOH. Will the T observed he greater than, less than, or equal to that in the first experiment, and why?
Why is it usually easier to use G to determine the spontaneity of a process rather than Su ?
Explain in your own words what is meant by the term entropy. Explain how both matter spread and energy spread are related to the concept of entropy.
Natural gas is mostly CH4. When it burns, the chemical reaction is CH4 g 2O2 g CO2 g 2H2O g The H of combustion of one mole of CH4 at 25.0 C is -890.9 kJ. Calculate q, w, and U under these conditions, assuming an external pressure of 1.07 atm.
A wad of steel wool (specific heat=0.45J/gC) at 25C is misplaced in a microwave oven, which later is accidentally turned on high. The oven generates microwaves of 13.5 cm wavelength at the rate of 925 moles of those photons per second. All of the photons are converted to high-heat energy, raising the temperature of the steel wool. Steel wool reacts explosively with the oxygen in the oven when the steel wool reaches 400.0C. If the steel wool explodes after 1.55 seconds, how many grams of steel wool were accidentally put into the oven?
A student performing a calorimetry experiment combined 100.0 ml. of 0.50 M HCI and 100.0 ml. of 0.50 M NaOH in a StyrofoamTM cup calorimeter. Both solutions were initially at 20.0 C, but when the two were mixed, the temperature rose to 23.2 C (a) Suppose the experiment is repeated in the same calorimeter but this time using 200 mL of 0.50 M HCl and 200.0 ml of 0.50 M NaOH. WIII the AT observed be greater than, less than, or equal to that in the first experiment, and why? (b) Suppose that the experiment is repeated once again in the same calorimeter, this time using 100 mL of 1.00 M HCI and 100.0 ml. of 1.00 M NaOH. Will the T observed be greater than, less than, or equal to that in the first experiment, and why?
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The reaction SO3(g)+H2O(l)H2SO4(aq) is the last step in the commercial production of sulfuric acid. The enthalpy change for this reaction is 227 kJ. In designing a sulfuric acid plant, is it necessary to provide for heating or cooling of the reaction mixture? Explain.
In a coffee-cup calorimeter, 100.0 mL of 1.0 M NaOH and 100.0 mL of 1.0 M HCI are mixed. Both solutions were originally at 24.6C. After the reaction, the final temperature is 31.3C. Assuming that all the solutions have a density of 1.0 g/cm3 and a specific heat capacity of 4.18 J/Cg, calculate the enthalpy change for the neutralization of HCl by NaOH. Assume that no heat is lost to the surroundings or to the calorimeter.
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