18. When 1 mole of ethene in the gas state reacts with 1 mole of water in the gas state, 1 mole of ethanol in the gas state is produced in an equilibrium reaction. If an equilibrium mixture contains 0.020 M ethene and 0.015 M water, the equilibrium concentration of ethanol is 1.35 M. The equilibrium constant for this reaction is 9000. (True or False)

18. When 1 mole of ethene in the gas state reacts with 1 mole of water in the gas state, 1 mole of ethanol in the gas state is produced in an equilibrium reaction. If an equilibrium mixture contains 0.020 M ethene and 0.015 M water, the equilibrium concentration of ethanol is 1.35 M. The equilibrium constant for this reaction is 9000. (True or False)

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter5: Introduction To Chemical Equilibrium

Section: Chapter Questions

Problem 5.8E: 5.8. The hemoglobin in blood establishes an equilibrium with oxygen gas very quickly. The...

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Methanol can be synthesized by means of the equilibriumreaction CO(g)+2H2(g)CH3OH(g) for which the equilibrium constant at 225°C is 6.08103. Assume that the ratio of the pressures of CO(g) and H2(g) is 1:2. What values should they have if the partial pressureof methanol is to be 0.500 atm?
For the given chemical equilibrium, these data are determined experimentally: T K 350K 3.76102 450K 1.86101 Determine H for this reaction.
. At high temperatures, elemental nitrogen and oxygen react with each other to form nitrogen monoxide. N2(g)+O2(g)2NO(g)Suppose the system is analyzed at a particular temperature, and the equilibrium concentrations arc found to be [N2]=0.041M. [O2]=0.0078M, and [NO]=4.710M. Calculate the value of K for the reaction.
5.8. The hemoglobin in blood establishes an equilibrium with oxygen gas very quickly. The equilibrium can be represented as where “heme” stands for hemoglobin and “” stands for the hemoglobin-oxygen complex. The value for the equilibrium constant for this reaction is about . Carbon monoxide also binds with hemoglobin by the following reaction: This reaction has an equilibrium constant of . Which reaction’s equilibrium lies farther toward products? Does your answer justify the toxicity of ?
In the text, the equation G=G+RTIn(Q) was derived for gaseous reactions where the quantities in Q were expressed in units of pressure. We also can use units of mol/L for the quantities in Q, specifical.ly for aqueous reactions. With this in mind, consider the reaction HF(aq)H+(aq)+F-(aq) for which Ka = 7.2 104 at 25C. Calculate G for the reaction under the following conditions at 25C. a. [HF] = [H+] = [F] = 1.0 M b. [HF] = 0.98 M, [H+] = [F] = 2.7 102M c. [HF] = [H+] = [F] = 1.0 105 M d. [HF] = [F] = 0.27 M, [H+] = 7.2 104M e. [HF] = 0.52 M, [F] = 0.67 M, [H+] = 1.0 103M Based on the calculated G values, in what direction will the reaction shift to reach equilibrium for each of the five sets of conditions?
Consider the system A(g)B(g) at25C. a. Assuming that GAo=8996J/molandGBo=11,718J/mol, calculate the value of the equilibrium constant for this reaction. b. Calculate the equilibrium pressures that result if 1.00 mole of A(g) at 1.00 atm and 1.00 mole of B(g) at 1.00 atm are mixed at 25C. c. Show by calculations that G = 0 at equilibrium.
5.16. In atmospheric chemistry, the following chemical reaction converts , the predominant oxide of sulfur that comes from combustion of S-containing materials, to , which can combine with to make sulfuric acid (and thus contribute to acid rain): (a) Write the expression for K for this equilibrium. (b) Calculate the value of for this equilibrium using the values in Appendix 2. (c) Calculate the value of K for this equilibrium. (d) If of and of are enclosed in a system in the presence of some liquid, in which direction would the reaction move?
The following reaction has KP=4.50105 at 720 K. N2(g)+3H2(g)2NH3 If a reaction vessel is filled with each gas to the partial pressures listed, in which direction will it shift to reach equilibrium? P(NH3)=93atm,P(N2)=48atm, and P(H2)=52
Because carbonic acid undergoes a second ionization, the student in Exercise 12.39 is concerned that the hydrogen ion concentration she calculated is not correct. She looks up the equilibrium constant for the reaction HCO,-(aq) «=* H+(aq) + COf'(aq) Upon finding that the equilibrium constant for this reaction is 4.8 X 10“H, she decides that her answer in Exercise 12.39 is correct. Explain her reasoning. A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H,CO,(aq) 5=6 H+(aq) + HCO,'(aq) K = 4.4 X 10'7She starts with 0.1000 A1 carbonic acid. W hat are the concentrations of all species at equilibrium?
The equilibrium constant for the reaction 2CrO42(aq)+2H+(aq)Cr2O72(aq)+H2O is 31014 . What must the pH be so that the concentrations of chromate and dichromate ion are both 0.10 M?
In Table 12.1 (←Sec. 12-3a) the equilibrium constant for the reaction ⇋ is given as 4.2 × 1052. If this reaction is so product-favored, why can large piles of yellow sulfur exist in our environment (as they do in Louisiana and Texas)?