1a. Do the chemical shifts of the benzene protons in the iodinated product confirm the structure drawn. Calculate the chemical shift of the benzene protons and compare to the spectrum 1b. Do the appearances of the benzene protons confirm the structure drawn. Use the j values for benzene signals to predict how the signals should appear and compare to the spectrum provided J ortho = 7-9 Hz J meta = 2-3 Hz J para = too small JEOL e HO TA 13 12 18 9 6 65 NH: S A I Ts T8 X:pwt per Miion Pt H. I.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
Section: Chapter Questions
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1a. Do the chemical shifts of the benzene protons in the iodinated product
confirm the structure drawn. Calculate the chemical shift of the benzene
protons and compare to the spectrum
1b. Do the appearances of the benzene protons confirm the structure drawn.
Use the j values for benzene signals to predict how the signals should appear
and compare to the spectrum provided
J ortho = 7-9 Hz
J meta = 2-3 Hz
J para = too small
JEOLO
Penane
ien take
pretonp
apie 4
E n take a
Caion Tie
Bevialon Tie
fine
-2-A-10as 1
29-A-202as i e
Curent
beta n
1D co
ite
nene
e
ec te
2. atel
onain
Ores
KONte
cane
luin
.
1.5
KOe med .
Proten
Tre
Snane
Tetai Bean
Belanatienelayla
erve dain
Te
a. te
deal
ngle
4.4
Bee de
T Mode
te re
a
penien
HO
NH:
S 84 82 KI LO 79 73 17 16 1s TA 13 12 71 70 69 68 67 66 65
X: parts per Million : Proton
H.
I.
Transcribed Image Text:1a. Do the chemical shifts of the benzene protons in the iodinated product confirm the structure drawn. Calculate the chemical shift of the benzene protons and compare to the spectrum 1b. Do the appearances of the benzene protons confirm the structure drawn. Use the j values for benzene signals to predict how the signals should appear and compare to the spectrum provided J ortho = 7-9 Hz J meta = 2-3 Hz J para = too small JEOLO Penane ien take pretonp apie 4 E n take a Caion Tie Bevialon Tie fine -2-A-10as 1 29-A-202as i e Curent beta n 1D co ite nene e ec te 2. atel onain Ores KONte cane luin . 1.5 KOe med . Proten Tre Snane Tetai Bean Belanatienelayla erve dain Te a. te deal ngle 4.4 Bee de T Mode te re a penien HO NH: S 84 82 KI LO 79 73 17 16 1s TA 13 12 71 70 69 68 67 66 65 X: parts per Million : Proton H. I.
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