(1I) According to the valence bond theory (VBT) answer the following regarding to [NicIj? complex. a) Draw orbital diagrams for the free nickel ion and the nickel ion the complex. b) Identify its type of hybridization and draw its geometrical shape. C) Predict whether it is inner or outer orbital complex. d) Calculate its magnetic moment. e) Discuss its Optical isomerism.

(1I) According to the valence bond theory (VBT) answer the following regarding to [NicIj? complex. a) Draw orbital diagrams for the free nickel ion and the nickel ion the complex. b) Identify its type of hybridization and draw its geometrical shape. C) Predict whether it is inner or outer orbital complex. d) Calculate its magnetic moment. e) Discuss its Optical isomerism.

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 70AP

See similar textbooks

Similar questions

Is optical isomerism applicable for the complex? If yes, draw the enantiomeric pair.
(a) Using Werner’s definition of valence, which property isthe same as oxidation number, primary valence or secondaryvalence? (b) What term do we normally use for the othertype of valence? (c) Why can NH3 serve as a ligand but BH3cannot?
Which of the shown complexes are chiral (Figure 1)?
Calculate the CFSE of the complex. (State how to search charge ligand Fe) Determine the hybridization of the metal central in the complex. (State the reason) Calculate the spin-only magnetic moment of the metal central in the complex. (State unpaired electron)
According to the theory of molecular orbitals, how are ligands classified and what effect do they have on the value of the octahedral field?
By using valence bond theory and ligand field theory, prove [Fe(acac)3] is aparamagnetic high spin octahedral complex. (acac = acetylacetonato). Give the explaination.
Work out the stoichiometries and structures of the neutral complexes, chromium carbonyl, rhenium carbonyl, and nickel carbonyl using the 18-electron rule. Then use valence bond theory to determine the hybridizations of the orbitals in each complex?
Draw the MO diagram of a complex ion based on the pi-effects of the ligand using ligand field theory
1. Draw two possible resonance structures for DMSO, where S is the central atom. What kind of bond exists beetween the S and O in DMSO? 2. Based upon these resonance structures, explain how DMSO can behave as an ambidentate ligand.
Pentaaminechlorocobalt (III) has ______ total ligand(s) and ______ counterion(s). The cobalt ion has an oxidation number of ______.
What is the expected number of Fe-Febondsper Fe atom in the complex ?
1. Co(NH3)63+ is a low-spin complex while CoF63- is a high-spin complex. Give a rational for this difference by applying valence bond theory (i.e. illustration the hybridization and filling up of the metal orbitals). Which is the inner orbital complex and the outer orbital complex?