Predict whether these complexes would be labile or inert and explain your choices. The magnetic moments are given in Bohr magneton (BM) after each compound.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
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a) Predict whether these complexes would be labile or inert and explain your choices. The
magnetic moments are given in Bohr magneton (BM) after each compound.
Magnetic moment
in Bohr magneton
Compound
Potassium hexaiodomanganate (IV)
3.82
Hexaammine iron (II) chloride
5.45
b) The high-spin dt complex [Cr(H:O)s]* is labile, but the low-spin đº complex ion
[Cr(CN)6]+ is inert. Explain
c) Calculate the orbital multiplicity for a Cr* assuming it is a free ion (Not complex).
BIU O
A
2
!!!
Transcribed Image Text:a) Predict whether these complexes would be labile or inert and explain your choices. The magnetic moments are given in Bohr magneton (BM) after each compound. Magnetic moment in Bohr magneton Compound Potassium hexaiodomanganate (IV) 3.82 Hexaammine iron (II) chloride 5.45 b) The high-spin dt complex [Cr(H:O)s]* is labile, but the low-spin đº complex ion [Cr(CN)6]+ is inert. Explain c) Calculate the orbital multiplicity for a Cr* assuming it is a free ion (Not complex). BIU O A 2 !!!
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