1/s) 10 [A] 0.660 [B] 1.23 105 4.01 1.23

Chemistry for Today: General, Organic, and Biochemistry
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Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Chapter8: Reaction Rates And Equilibrium
Section: Chapter Questions
Problem 8.29E
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For the reaction A + B C + D, various initial rate measurements were run beginning with A and B only,
and beginning with C and D only. From the data below, calculate the rate law for both the forward and backward
reactions. Then determine the equilibrium constant for the reaction.
Rate (M/s)
1.081 x 10
6.577 x 10
6.568 x 10
[A]
0.660
[B]
1.23
4.01
1.23
2.25
4.01
Rate (M/s)
7.805 x 10
1.290 x 10"
1.300 x 10
[C]
2.88
[D]
0.995
2.88
1.01
1.65
1.65
Transcribed Image Text:For the reaction A + B C + D, various initial rate measurements were run beginning with A and B only, and beginning with C and D only. From the data below, calculate the rate law for both the forward and backward reactions. Then determine the equilibrium constant for the reaction. Rate (M/s) 1.081 x 10 6.577 x 10 6.568 x 10 [A] 0.660 [B] 1.23 4.01 1.23 2.25 4.01 Rate (M/s) 7.805 x 10 1.290 x 10" 1.300 x 10 [C] 2.88 [D] 0.995 2.88 1.01 1.65 1.65
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