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+ 2 CH3CO2H NACIO + H₂O HOCI + Br HOBr + H+ + erall reaction: H₂O 2 HOCI + HOBr + Br2 + H₂O +2

+ 2 CH3CO2H NACIO + H₂O HOCI + Br HOBr + H+ + erall reaction: H₂O 2 HOCI + HOBr + Br2 + H₂O +2

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.24P: Pyridine exhibits a UV transition of the type n at 270 nm. In this transition, one of the unshared...
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Bromine is produced in situ to react with the aromatic ring. What is the redox reaction that occurs between NACIO (in bleach) and NaBr in acetic acid to form Br2? NOTE: Use your general chemistry skills to complete the five equilibria reactions below and then write a final balanced equation. Think about what you start and end with to write the overall reaction. + 2 CH3CO2H NACIO + H₂O HOCI + Br HOBr + H+ + Overall reaction: H₂O 2 HOCI + HOBr + Br2 + H₂O + 2
Transcribed Image Text:Bromine is produced in situ to react with the aromatic ring. What is the redox reaction that occurs between NACIO (in bleach) and NaBr in acetic acid to form Br2? NOTE: Use your general chemistry skills to complete the five equilibria reactions below and then write a final balanced equation. Think about what you start and end with to write the overall reaction. + 2 CH3CO2H NACIO + H₂O HOCI + Br HOBr + H+ + Overall reaction: H₂O 2 HOCI + HOBr + Br2 + H₂O + 2
● ● Aromatic Bromination and Green Chemistry Two step synthesis and identification of product Will use vacuum filtration and analysis with m.p., IR, and NMR Day 1: Protection of Aniline Nitrogen (Amide Formation) ● Modifying aniline through reaction with acetic anhydride Day 2: Aromatic Bromination Monobromination of an activated aromatic compound Evaluation of directing effects by the isomeric product obtained Modification of procedure from Luong et al, J. Chem Ed. 2012, 89, 1061-1063 NH₂ aniline NH NaBr, NaClO AcOH, EtOH acetanilide para NH ΝΗ Br ortho meta Which position is brominated? (ortho, meta, or para)
Transcribed Image Text:● ● Aromatic Bromination and Green Chemistry Two step synthesis and identification of product Will use vacuum filtration and analysis with m.p., IR, and NMR Day 1: Protection of Aniline Nitrogen (Amide Formation) ● Modifying aniline through reaction with acetic anhydride Day 2: Aromatic Bromination Monobromination of an activated aromatic compound Evaluation of directing effects by the isomeric product obtained Modification of procedure from Luong et al, J. Chem Ed. 2012, 89, 1061-1063 NH₂ aniline NH NaBr, NaClO AcOH, EtOH acetanilide para NH ΝΗ Br ortho meta Which position is brominated? (ortho, meta, or para)
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