2/ Please explain the answer in detail The J = 0 to j = 1 transition for carbon monoxide (12C160) occurs at 1.153 × 105 MHz. Calculate the value of the bond length in carbon monoxide.
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- A space probe was designed to see 13CO in the atmosphere of Saturn by looking for lines in its rotational spectrum. If the bond length of CO is 112.8 pm, at what wave number do the first three rotational transitions appear?The moment of inertia of CH4 can be calculated from the expression I=8/3 mHR2 where R is the C-H bond length (109 angstrom or 109 x 1012 m). a. What is the lowest possible rotational energy of the CH4 molecule and what is the value of quantum number l associated with that rotational energy? b. Calculate the rotational energy of the molecule in the first excited state (when quantum number l = 1). c. Determine the degeneracy of the first excited state. Explain what is meant by rotational energy degeneracy.Calculate the size of the quantum involved in the excitation of an electronic motion of frequency 1.0 x 1015 Hz. Ans: 400 kJ/mol
- Calculate the separation between the two lowest levels for an O2 molecule in a one-dimensional container of length 5.0 cm. At what value of n does the energy of the molecule reach 1/2kT at 300 K, and what is the separation of this level from the one immediately below?Q/ The bond length of the C0O molecule is 112.8 pm. Calculate the following (a) The reduced mass. (b) The rotational constant of CO when moment of inertia (I) is 1.4486 x 1046 kg.m² (c) Calculate the wavelength of the photon absorbed when a CO molecule initially in the J=2 level. makes a transition to the J=3 level.Calculate the rotational energy of CO at J=2 given a bond length of 1.0 Å. unit in eV.
- (a) Express the moment of inertia of an octahedral AB6 molecule in terms of its bond lengths and the masses of the B atoms. (b) Calculate the rotational constant of 32S19F6 , for which the S—F bond length is 158 pm.R(x)=x2+9x+8/x+1 What is the equation of the vertical asymptote(s) of R(x)?The rotational constant of 127I35CI is 3.423 GHz. Ca lculate the ICI bond length.
- The J = 0 to J = 1 rotational transition of the CO molecule occurs at a frequency of 1.15 x 1011 Hz.(A) Use this information to calculate the moment of inertia of the molecule. (B) Calculate the bond length of the molecule.A rotating methane molecule is described by the quantum numbers J, MJ, and K. (a) For methane, how many rotational states have an energy equal to hBJ(J + 1) with J= 8? (b) Now consider chloromethane. How many rotationalstates have an energy equal to hBJ(J + 1) with J = 8?For 14N2, Δ ᷉ G values for the transitions v = 1 ← 0, 2 ← 0, and 3 ← 0 are, respectively, 2345.15, 4661.40, and 6983.73 cm−1. Calculate ᷉v and xe. Assume ye to be zero.