2) You are tasked with determining the barium content of a samplecontaining barium nitrate mixed with rubidium nitrate. The sample isweighed, dissolved into 50.0mg water, and treated with xs 0.500Msodium sulfate. The acid fully ionizes in this experiment. A whiteprecipitate forms which is washed, filtered, and weighed multipletimes, according to the data given below:Mass of sample0.425gMass of thoroughly dried filter paper1.462gMass of precipitate+filter after 1st drying1.755gMass of precipitate+filter after 2nd drying1.699gMass of precipitate+filter after 3rd drying1.698gA] for the chemical reaction that occurs forming the precipitate:(i) write the balanced net-ionic equation for the reaction(ii) explain why the net-ionic equation optimally represents theprocess

The balanced net-ionic equation for the reaction is shown in equation (2).

Answered: 2) You are tasked with determining the…

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter13: Titrations In Analytical Chemistry

Section: Chapter Questions

Problem 13.22QAP

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Twenty-five milliliters of a solution (d=1.107g/mL)containing 15.25% by mass of sulfuric acid is added to 50.0 mL of 2.45 M barium chloride. (a) What is the expected precipitate? (b) How many grams of precipitate are obtained? (c) What is the chloride concentration after precipitation is complete?
A student carried out an experiment trying to prepare tetra-methyl-ammonium tri-iodide.The student weighed 1.13 g tetra-methyl-ammonium iodide into a beaker containing 25 mL ethanol, and then added 1.57 g of iodine. The mixture was heated gently, whilst stirring, on a hotplate until tetra-methyl-ammonium iodide, a white powder, was completely dissolved. After the mixture was allowed to cool down to room temperature, the mixture was further cooled on ice. After filtration on a Buechner funnel, washing with diethyl ether and leaving it under vacuum suction for a couple of minutes, the student recovered the product and weighed it. The mass of the obtained tetra-methyl-ammonium triiodide was 1.62 g.What is the yield of the reaction in percent [%]? For the calculation, assume that the product is completely dry and pure, so there are no impurities like side-products, unreacted educts, or solvent residues.
You are required to standardize a dilute solution of sulphuric acid, and undertake the following steps:(i) 4.805 g of solid sodium tetraborate (Na2B4O7) are added to a 250 mL volumetric flask, and the solution made up to the mark with distilled water.(ii) 25.00 mL aliquots of the stock solution from (i) are transferred to conical flasks, for titration against the sulphuric acid solution in the burette.(iii) You perform titrations using two different indicators: bromocresol green, and phenolphthalein.With bromocresol green, the average titre volume is 22.50 cm3, while with phenolphthalein, the average volume is 9.50 cm3.(a) Write the balanced equation for the reaction between Na2B4O7 and sulphuric acid
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A solid sample containing chloride ion is analyzed by argentimetric titration to find the percentage chloride by mass. The procedure involves the preparation of a solution made from primary standard sodium chloride (molar mass = 58.443 g mol-1). Aliquots of NaCl solution will be titrated with silver nitrate solution to accurately determine the AgNO3 concentration. The standardized silver nitrate will be used to titrate aliquots of unknown chloride solution, thus allowing for the determination of the percentage chloride in the original solid sample. To detect the endpoint of the titration the adsorption indicator dichlorofluorescein is used. Please solve for the highlighted portions.
Titration of a 25.00 mL sample of acid rain required 12.4 mL of 0.009879 M NaOH to reach the end point. If we assume that the acidity of the rain is due to the presence of sulfuric acid, what was the concentration (in mol/l and %) of sulfuric acid in this sample of rain?
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After studying the separation scheme for Group III cations and using your background knowledge on separation of Group I and Group II cations: (a) devise a flow chart or schematic diagram to separate and confirm the presence of the given ions in the solution below; (b) write the chemical formula of the precipitates formed; and (c) provide a brief explanation about your schematic diagram.
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Mark and John, two vinegar enthusiasts, are each tasked to determine the acetic acid content of their respective vinegar concoctions by titration. First, a 1 M-labeled KOH solution was standardized against the KHP (MW = 204.22 g/mol) standard that is 99.4% pure. In the process, 0.540 g KHP was found to require 2.80 mL of the KOH solution to completely react up to the phenolphthalein endpoint. Then, Mark and John both prepared their samples by taking 10.0-mL aliquots of each vinegar and diluting them to 25.0 mL. Using the same titrant and indicator, Mark’s vinegar required 18.60 mL of the standardized titrant to reach the endpoint, while John’s vinegar required 16.50 mL of the same titrant to reach the same endpoint. Question: What is the acetic acid concentration of Mark’s and John’s vinegar in molarity given that the Concentration of KOH is 9386 M?
Mark and John, two vinegar enthusiasts, are each tasked to determine the acetic acid content of their respective vinegar concoctions by titration. First, a 1 M-labeled KOH solution was standardized against the KHP (MW = 204.22 g/mol) standard that is 99.4% pure. In the process, 0.540 g KHP was found to require 2.80 mL of the KOH solution to completely react up to the phenolphthalein endpoint. Then, Mark and John both prepared their samples by taking 10.0-mL aliquots of each vinegar and diluting them to 25.0 mL. Using the same titrant and indicator, Mark’s vinegar required 18.60 mL of the standardized titrant to reach the endpoint, while John’s vinegar required 16.50 mL of the same titrant to reach the same endpoint. Question: What is the exact concentration of the KOH titrant in molarity? What is the balanced chemical equation between the analyte and the titrant? What is the color transition (color X ? color Y) expected throughout the course of titration?

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