2) You are tasked with determining the barium content of a samplecontaining barium nitrate mixed with rubidium nitrate. The sample isweighed, dissolved into 50.0mg water, and treated with xs 0.500Msodium sulfate. The acid fully ionizes in this experiment. A whiteprecipitate forms which is washed, filtered, and weighed multipletimes, according to the data given below:Mass of sample0.425gMass of thoroughly dried filter paper1.462gMass of precipitate+filter after 1st drying1.755gMass of precipitate+filter after 2nd drying1.699gMass of precipitate+filter after 3rd drying1.698g C] In the filtrate solution, is [Na'] less than, equal to, or greater thanthe [NO,] level? Justify your answer.

Observing the given information, it is clear that excess amount of 0.500M sodium sulfate is added.

Answered: 2) You are tasked with determining the…

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter10: Solutions

Section: Chapter Questions

Problem 65QAP: Twenty-five milliliters of a solution (d=1.107g/mL)containing 15.25% by mass of sulfuric acid is...

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Twenty-five milliliters of a solution (d=1.107g/mL)containing 15.25% by mass of sulfuric acid is added to 50.0 mL of 2.45 M barium chloride. (a) What is the expected precipitate? (b) How many grams of precipitate are obtained? (c) What is the chloride concentration after precipitation is complete?
A student carried out an experiment trying to prepare tetra-methyl-ammonium tri-iodide.The student weighed 1.13 g tetra-methyl-ammonium iodide into a beaker containing 25 mL ethanol, and then added 1.57 g of iodine. The mixture was heated gently, whilst stirring, on a hotplate until tetra-methyl-ammonium iodide, a white powder, was completely dissolved. After the mixture was allowed to cool down to room temperature, the mixture was further cooled on ice. After filtration on a Buechner funnel, washing with diethyl ether and leaving it under vacuum suction for a couple of minutes, the student recovered the product and weighed it. The mass of the obtained tetra-methyl-ammonium triiodide was 1.62 g.What is the yield of the reaction in percent [%]? For the calculation, assume that the product is completely dry and pure, so there are no impurities like side-products, unreacted educts, or solvent residues.
You are required to standardize a dilute solution of sulphuric acid, and undertake the following steps:(i) 4.805 g of solid sodium tetraborate (Na2B4O7) are added to a 250 mL volumetric flask, and the solution made up to the mark with distilled water.(ii) 25.00 mL aliquots of the stock solution from (i) are transferred to conical flasks, for titration against the sulphuric acid solution in the burette.(iii) You perform titrations using two different indicators: bromocresol green, and phenolphthalein.With bromocresol green, the average titre volume is 22.50 cm3, while with phenolphthalein, the average volume is 9.50 cm3.(a) Write the balanced equation for the reaction between Na2B4O7 and sulphuric acid
The following analytical procedures were used for the determination of chlorate (ClO3-). 10.00 mL of solutionA containing chlorate is analyzed. The chlorate is reduced with granulated zinc (to chloride).The excess zinc is dissolved in acid, after which the sample is filtered. The filtered sample is added70.00 mL 0.100 M AgNO3 solution dropwise. The precipitate is filtered off, washed and dried.It weighs 0.6003 grams. Calculate the chlorate concentration in solution A
A student was asked to determine the concentration of ammonia, a volatile substance, in a commercially available cloudy ammonia solution used for cleaning. First the student pipetted 25.00 mL of the cloudy ammonia solution into a 250.0 mL conical flask. 50.00 mL of 0.100 mol L-¹ HCl(aq) was immed added to the conical flask which reactedwith the ammonia in solution. The excess (unreacted) HC1 was then titrated with 21.50 mL 0. 050 M Na2CO3 (aq). Calculate the concentration of the ammonia in the cloudy ammonia solution.
Fifty food supplement tablets with a total mass of 66.393 g were crushed into powder to analyse the content of FeSO4·7H2O. 2.988 g of the powder were dissolved in HNO3 and heated to convert all the iron to Fe3+. Addition of aqueous NH3 caused quantitative .precipitation of Fe2O3· X H2O, which was ignited to give 0.0640 g of Fe2O3. Determine the average weight of FeSO4·7H2O in each tablet.
A dried sample of commercial salt was prepared by a coning and quartering. A 0.837-g sample of the salt was dissolved and diluted to 250.0 mL in a volumetric flask. Repeat 10.00-mL aliquots of this solution were titrated with a 0.057 M silver nitrate solution, requiring 9.07 mL to reach equivalence. Calculate the mass (g) of NaCl in the original sample.
A solid sample containing chloride ion is analyzed by argentimetric titration to find the percentage chloride by mass. The procedure involves the preparation of a solution made from primary standard sodium chloride (molar mass = 58.443 g mol-1). Aliquots of NaCl solution will be titrated with silver nitrate solution to accurately determine the AgNO3 concentration. The standardized silver nitrate will be used to titrate aliquots of unknown chloride solution, thus allowing for the determination of the percentage chloride in the original solid sample. To detect the endpoint of the titration the adsorption indicator dichlorofluorescein is used. Please solve for the highlighted portions.
Titration of a 25.00 mL sample of acid rain required 12.4 mL of 0.009879 M NaOH to reach the end point. If we assume that the acidity of the rain is due to the presence of sulfuric acid, what was the concentration (in mol/l and %) of sulfuric acid in this sample of rain?
To determine , by gravimetric analysis, the concentration of barium ions (Ba2+) in a given solution, 25.00cm3 of it are pipetted into a beaker and an excess of dilute sulphuric acid is added to it. The precipitate then obtained (BaSO4) is filtered, dried and weighed. The mass of the precipitate is found to be 1.167g Calculate the concentration of barium ions in the solution? (only 2 decimal places). _________Mol/L
In the common process for the manufacture of nitric acid, sodium nitrate is treated with aq. sulphuric acid containing 95% H2SO4. In order that the resulting "niter cake" may be fluid; it is desirable to use sufficient acid so that there will be 34% H2SO4 by wt in the final cake. This excess H2SO4 will actually be in combination with the Na2SO4 in the cake, forming NaHSO4, although for purposes of computation it may be assumed to be free acid. The cake will contain 1.5% water and the reaction will go to completion, but 2% of the HNO3 formed will remain in the cake. Assume that the NaNO3 used is dry and pure. Calculate per 100 kg of NaNO3 charged: (a) wt and % composition of the niter cake (b) wt of aqueous acid to be used (c) wt of water vapor and nitric acid distilled from the niter cake.
After studying the separation scheme for Group III cations and using your background knowledge on separation of Group I and Group II cations: (a) devise a flow chart or schematic diagram to separate and confirm the presence of the given ions in the solution below; (b) write the chemical formula of the precipitates formed; and (c) provide a brief explanation about your schematic diagram.

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