2. (a) The v(CO) of isoelectronic series [Mn(CO)], [Cr(CO)6] and [V(CO) are 2090 cm¹ 2000cm¹ and 1860 cm¹, respectively. Why is this difference observed in the band positions?

Principles of Modern Chemistry
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Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
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2. (a) The v(CO) of isoelectronic series [Mn(CO)]*, [Cr(CO)] and
are 2090 cm¹ 2000cm¹ and 1860 cm¹, respectively.
Why is this difference observed in the band positions?
[V(CO)
Transcribed Image Text:2. (a) The v(CO) of isoelectronic series [Mn(CO)]*, [Cr(CO)] and are 2090 cm¹ 2000cm¹ and 1860 cm¹, respectively. Why is this difference observed in the band positions? [V(CO)
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