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- The thiourea in a 1.455 g sample of organic material was extracted into a dilute sulfuric acid solution and titrated with 37.31 mL of 0.009372 M Hg2+ via reaction: 4(NH2)2CS + Hg2+ →[(NH2)2CS]4 Hg2+ P.S. Answer only the last two letters of the following questions. (Only C and D) a. Is this an example of total analysis technique or concentration technique? Explain. b. Calculate the percent (NH2)2CS ( 76.12 g/mol) in the sample. c. What is classification of the analysis based on the amount of sample and amount of analytes present? Explain. d. If the true value is 10.00%, calculate the absolute and relative error.1. Find the number of millimoles of solute in a. 226 ?? of 0.320 ? HClO4. b. 25.0 ? of 8.05 ? 10−3 ? K2CrO4. c. 6.00 ? of an aqueous solution that contains 6.75 ??? of AgNO3. d. 537 ?? of 0.0200 ? KOH. 2. Describe the preparation of a. 5.00 ? of 0.0500 ? KMnO4 from the solid reagent. b. 4.00 ? of 0.250 ? HClO4, starting with an 8.00 ? solution of the reagent. c. 400 ?? of a solution that is 0.0250 ? in I2, starting with MgI2. d. 200 ?? of 1.00% (?/?) aqueous CuSO4 from a 0.365 ? CuSO4 solution. e. 1.50 ? of 0.215 ? NaOH from the concentrated commercial reagent [50% NaOH (w/w), ?? ?? = 1.525]. f. 1.50 ? of a solution that is 12.0 ??? in K+, starting with solid K4Fe(CN)6. 3. Exactly 75.00 ?? of a 0.3132 ? solution of Na2SO3 were treated with 150.0 ?? of 0.4025 ? HClO4 and boiled to remove the SO2 formed. a. What was the mass in grams of SO2 that was evolved? b. What was the concentration of the unreacted reagent (Na2SO3 or HClO4) after thereaction was complete?why would you add 10 mL of concentrate to 490 mL of water if you were instructed to dilute the concentrate 1:50 with water and you were was using a bottle with a 500 mL capacity
- A mixture of pure BaCO3 and pure Na2CO3 weighs 1.000 g and has the total neutralizing power of 15.37 meq of CaCO3. Calculate the percentage of combined CO2 in the mixture and the weight of Li2CO3 that has the same neutralizing power as 1.000 g of the above mixture. Instructions: Include up to 4 decimal places See sample photo for the format of solution0.5 g mixture of (0.1 N KCI and 4 points KBr) is required to 58.03 mL of 0.1 N AGNO3 to precipitate both bromide and chloride as AgCl and AgBr. Calculate the weight percentage for each of the AgCl and AgBr in a mixture if you know that the molecular weight of KCI = 74.5 and of KBr = 119 * %3DA worker in a dye factory accidentally mixed the compound labeling and you were tasked in identifying one of the dyes. One solution states it contained a saturated 0.25302% dye by mass in ethanol solvent. By measuring its weight and volume, the density of the solution was determined to be 0.79046 g/mL. The solution was further analyzed and determined to have a concentration of 0.00239266 M pink dye. What is the molecular weight of the dye? Hint: %w/v
- a) What mass of Fe(NH4)2(SO4)2•2H2O(s) is required to prepare a 500 mL solution containing 100 ppm (m:v) in Fe? b) Using this stock solution, what aliquot must be used to prepare calibration solutions, 100 mL volume, of the following concentrations: 0.100 ppm, 0.500 ppm, 2.00 ppm, 4.00 ppm, and 7.00 ppm.Please answer as soon as possible. Thank you! A 10.000-g cocoa powder sample was dissolved in concentrated acid and then diluted to 100.00 mL using distilled water. The solution was found to contain 5.45 uM Fe. Calculate concentration of Fe (MM: 55.845) in the cocoa powder sample in parts-per-million (ppm) (weight by volume).The first goal is to make the oxalic acid standard solution. You measure 1.5232 g of oxalic acid on an analytical balance, add it to a 250-mL volumetric flask and add deionized H2O to a final volume of 250.0 mL. Molar mass of H2C2O4•2H2O = 126.07 g/mol Mass of H2C2O4•2H2O = 1.5232g Volume of H2C2O4•2H2O solution = 250.0mL What is the Molarity H2C2O4 standard solution ?
- Can you help me determine the required amount of 500mg ascorbic acid tablets to puverize the necessary amount of distilled water to make the desired concentration of stock solution (0.1M) Show complete and justifiable computations pls.How do I prepare these solutions? I do not know what volumes or molarities to be added from the initial step. Thank you. 1. Prepare a fresh stock solution of 50 cm3of 0.2% ascorbic acid. 2. Prepare 5 standard solutions of ascorbic acid in volumetric flasks of 25 cm3. 3. To each volumetric flask add 0.5 cm3 of 0.5M acetate buffer and different volumes of 0.2% ascorbic acid to make 0.01 mM, 0.02 mM, 0.03 mM, 0.04 mM and 0.05 mM solutions. Dilute to the mark with distilled water.You are asked to make the compound [Ni(en)3]SO4. - By using 2.611 grams of NiSO4*6H2O (s) you dissolve the sample in deionized water completely. - You then add 10ml of 25% en into the solution and mix until a single product forms - When the addition of the en is complete, you then add 15ml of ethanol and mix. - using a bench vaccine and Buchner funnel, you filter the precipitate while carefully breaking up the solid until powder form. - the product is the washed with 15ml of ethanol and 15ml of acetone. Powder the solid and leave to dry Which is the limiting reagent? Write a balanced chemical equation for the reaction. How many miles of the product can you theoretically prepare?
