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- Gold metal will dissolve only in aqua regia, a mixture of concentrated hydrochloric acid and concentrated nitric acid in a 3:1 volume ratio. The products of the reaction between gold and the concentrated acids are AuCl4-(aq), NO(g), and H2O. The equation for this reaction where HNO3 and HCl are strong acids is Au(s)+4Cl(aq)+4H+(aq)+NO3(aq)AuCl4(aq)+NO(g)+2H2O(a) What stoichiometric ratio of hydrochloric acid to nitric acid should be used? (b) What volumes of 12 M HCl and 16 M are HNO3 required to furnish the Cl- and NO3- ions to react with 25.0 g of gold?Write balanced net ionic equations for the following reactions in acid solution. (a) Liquid hydrazine reacts with an aqueous solution of sodium bromate. Nitrogen gas and bromide ions are formed. (b) Solid phosphorus (P4) reacts with an aqueous solution of nitrate to form nitrogen oxide gas and dihydrogen phosphate (H2PO4-) ions. (c) Aqueous solutions of potassium sulfite and potassium permanganate react. Sulfate and manganese(II) ions are formed.When 85.0 mL of 0.250 M Ba(OH)2 solution is added to 85.00 mL of 0.250 M Al (NO3)3 solution, a white gelatinous precipitate of Al(OH)3; is formed. Assuming 100% yield, (a) what mass (in grams) of Al(OH)3 is formed? (b) what is the molarity of each of the ions Ba2+, OH-, Al3+, NO3- in the resulting solution?
- Use the appropriate tables to calculate H for (a) the reaction between MgC03(s) and a strong acid to give Mg2+(aq), CO2(g), and water. (b) the precipitation of iron(III) hydroxide from the reaction between iron(III) and hydroxide ions.The iron content of hemoglobin is determined by destroying the hemoglobin molecule and producing small water-soluble ions and molecules. The iron in the aqueous solution is reduced to iron(II) ion and then titrated against potassium permanganate. In the titration, iron(ll) is oxidized to iron(III) and permanganate is reduced to manganese(II) ion. A 5.00-g sample of hemoglobin requires 32.3 mL of a 0.002100 M solution of potassium permanganate. The reaction with permanganate ion is MnO4(aq)+8H+(aq)+5Fe2+(aq)Mn2+(aq)+5Fe3+(aq)+4H2O What is the mass percent of iron in hemoglobin?Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?
- One of the few industrial-scale processes that produce organic compounds electrochemically is used by the Monsanto Company to produce1,4-dicyanobutane. The reduction reaction is 2CH2CHCH+2H++2eNC(CH2)4CN The NC(CH2)4CN is then chemically reduced using hydrogen gas to H2N(CH2)6NH2, which is used in the production of nylon. What current must be used to produce 150.kg NC(CH2)4CN per hour?The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.Given HFH+(aq)+F(aq)Ka=6.9104HF(aq)+F(aq)H2(aq)K=2.7 calculate K for the reaction 2HF(aq)H+(aq)+HF2(aq)
- Lead poisoning has been a hazard for centuries. Some scholars believe that the decline of the Roman Empire can be traced, in part, to high levels of lead in water from containers and pipes, and from wine that was stored in leadglazed containers. If we presume that the typical Roman water supply was saturated with lead carbonate, PbCO3 (Ksp = 7.4 1014), how much lead will a Roman ingest in a year if he or she drinks 1 L/day from the container?Iodine can be prepared by allowing an aqueous solution of hydrogen iodide to react with manganese dioxide, MnO2. The reaction is 2I(aq)+4H+(aq)+MnO2(s)Mn2+(aq)+2H2O+I2(s) If an excess of hydrogen iodide is added to 0.200 g of MnO2, how many grams of iodine are obtained, assuming 100% yield?Aluminum is produced commercially by the electrolysis of Al2O3 in the presence of a molten salt. If a plant has a continuous capacity of 1.00 million A, what mass of aluminum can be produced in 2.00 h?