2. MF Relative Intensity 100- 80 40 20 0-|rrrrrr 25 -5 50 75 m/z 100 125 150

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter32: Radiochemical Methods
Section: Chapter Questions
Problem 32.13QAP
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Show complete details.

A) Identify the structure of the important fragments. 

B) Show the arrow pushing mechanism to form the significant fragments. 

C) Suggest possible structure based on MS and IR data.

 

2. MF C₂H₂O
100
Relative Intensity
80-
40
20
0
25
50
75
m/z
100
m
125
mpetithy
150
27.0
28.0
29.0
38.0
39.0
50.0
51.0
51.5
52.0
53.0
54.0
55.0
61.0
62.0
63.0
65.0
74.0
75.0
76.0
77.0
78.0
79.0
89.0
91.0
101.0
102.0
103.0
104.0
105.0
131.0
132.0
133.0
1.5
1.1
1.0
1.2
3.7
8.6
21.2
1.1
5.5
1.2
1.0
1.1
1.1
2.5
5.7
1.1
5.3
4.7
5.1
35.7
26.1
1.7
1.2
2.5
1.5
8.9
54.5
27.4
3.5
100.0
74.8
7.3
Transcribed Image Text:2. MF C₂H₂O 100 Relative Intensity 80- 40 20 0 25 50 75 m/z 100 m 125 mpetithy 150 27.0 28.0 29.0 38.0 39.0 50.0 51.0 51.5 52.0 53.0 54.0 55.0 61.0 62.0 63.0 65.0 74.0 75.0 76.0 77.0 78.0 79.0 89.0 91.0 101.0 102.0 103.0 104.0 105.0 131.0 132.0 133.0 1.5 1.1 1.0 1.2 3.7 8.6 21.2 1.1 5.5 1.2 1.0 1.1 1.1 2.5 5.7 1.1 5.3 4.7 5.1 35.7 26.1 1.7 1.2 2.5 1.5 8.9 54.5 27.4 3.5 100.0 74.8 7.3
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