2. Silver ion forms a complex ion with cyanide (Ag(CN)2). Calculate the solubility of Agl in 1.00 M KCN. See page 1 for Kf and Ksp values.

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Chapter16: Solubility And Complex Ion Equilibria
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2. Silver ion forms a complex ion with cyanide (Ag(CN)2). Calculate the solubility of Agl in 1.00 M KCN. See page 1 for Kf
and Ksp values.
Transcribed Image Text:2. Silver ion forms a complex ion with cyanide (Ag(CN)2). Calculate the solubility of Agl in 1.00 M KCN. See page 1 for Kf and Ksp values.
Complex lon
Ag(NH3)2
Ag(CN)₂
Cu(CN)2
Cu(NH3)2+
Cd(CN)2
Cdl
HgCl2-
Hgl/
Hg(CN)2-
Co(NH3)+
Zn(NH,)+
Salt
Agl
Pbl2
PbCl₂
Hg₂Cl₂
AgCl
2+
Formation
Constant (K₁)
1.5 × 107
1.0 × 1021
1.0 × 1025
5.0 × 10¹3
7.1 × 10¹6
2.0 × 106
1.7 × 10¹6
2.0 × 10³0
2.5 × 1041
5.0 × 10³1
2.9 × 10⁹
Ksp
1.5 × 10-16
1.4 x 10-8
1.6 x 10-5
1.1 x 10-¹
1.6 x 10-10
-18
Transcribed Image Text:Complex lon Ag(NH3)2 Ag(CN)₂ Cu(CN)2 Cu(NH3)2+ Cd(CN)2 Cdl HgCl2- Hgl/ Hg(CN)2- Co(NH3)+ Zn(NH,)+ Salt Agl Pbl2 PbCl₂ Hg₂Cl₂ AgCl 2+ Formation Constant (K₁) 1.5 × 107 1.0 × 1021 1.0 × 1025 5.0 × 10¹3 7.1 × 10¹6 2.0 × 106 1.7 × 10¹6 2.0 × 10³0 2.5 × 1041 5.0 × 10³1 2.9 × 10⁹ Ksp 1.5 × 10-16 1.4 x 10-8 1.6 x 10-5 1.1 x 10-¹ 1.6 x 10-10 -18
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