22. An unprotonated primary amino group in a blood protein can n- is react with carbon dioxide to form a carbamate as shown here: R-NH2 + CO2→R-NH–COO¯+ H+ de Carbamate al The rate constant k for this reaction is 4950 M.s. a. What is the M. order of this reaction? b. Calculate the velocity of the reaction of an a-amino group in a blood protein at 37°C if its concentration is 0.6 mM and the partial pressure of carbon dioxide is 40 torr. (Hint: Convert the units of partial pressure to molar concentration using the ideal gas law. The value of R is 0.0821 L·atm · K-l · mol-1.) c. How would the rate constant for this reaction vary with pH? Explain. ed of d. What CO, partial pressure is required to yield a velocity of 0.045 M·s for the reaction?
22. An unprotonated primary amino group in a blood protein can n- is react with carbon dioxide to form a carbamate as shown here: R-NH2 + CO2→R-NH–COO¯+ H+ de Carbamate al The rate constant k for this reaction is 4950 M.s. a. What is the M. order of this reaction? b. Calculate the velocity of the reaction of an a-amino group in a blood protein at 37°C if its concentration is 0.6 mM and the partial pressure of carbon dioxide is 40 torr. (Hint: Convert the units of partial pressure to molar concentration using the ideal gas law. The value of R is 0.0821 L·atm · K-l · mol-1.) c. How would the rate constant for this reaction vary with pH? Explain. ed of d. What CO, partial pressure is required to yield a velocity of 0.045 M·s for the reaction?
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.99QE
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