2262 Sat Aor 61 Which one of the following compounds is the strongest acid?CNH2-NH2-CO2HOHCI-СОНCHCHCAB2. Which one of the following amines will not produce an amide when mixed with an acid chloride?NHPHCH,NH2PHNH2Et,NHAC3. What is the major product of the following sequence of reactions?CH3 1) NBS, hv(excess)C(OH)3CHOCO2HCH2O2) NaOH, H20(excess)AВC4. What is the major product of the following intramolecular aldol condensation reaction?ENaOHH20(dehydration)AC3.D.B

Carboxylic acids are more acidic than alcohols due to conjugate base stability R-COOH…

Answered: 2262 Put all answers 1 Which one of the…

2262 Put all answers 1 Which one of the following compounds is the strongest acid? -HO- сон CH CI- COH CI- -NH2 -CO2H C lo when mixed with an aci

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter24: Amines And Heterocycles

Section24.6: Synthesis Of Amines

Problem 11P

See similar textbooks

Related questions

Q: Nitrogen and water react to form nitrogen monoxide and hydrogen, like this: N2(9) + 2 H,O(g) - 2…

Q: H OCH3 Na OČCH3 Br DMSO H. DMSO = dimethyl sulfoxide Use the wedge/hash bond tools to indicate…

A: The structural formula for the substitution product of the reaction is:

Q: (c) dependence of acidity and basicity on oxidation state

A: The oxidation state have direct impact on acidity and basicity of element. So we will consider…

Q: Show the retrosynthesis mechanism of this equation with curved arrows representing electron transfer…

A: Note : 1-Butene on hydroboration and oxidation produces the 1-butanol. Benzoic acid and 1-butanol…

Q: 5.3 × 1025 molecules of CO, a oduced in a combustion react hat is the mass in kg of CO2 th pduced?

A: Given, Number of molecules = 6.3×1025 moles = Number of molecules/NA = 6.3×1025/6.022×1023 =…

Q: Four liquids are described in the table below. Use the second column of the table to explain the…

Q: Use the following equations to calculate the heat of the reaction for the synthesis of diborane.…

Q: Calculate the solubility of PbF, in water at 25 °C. You'll find K, data in the ALEKS Data tab. Round…

Q: A stock solution of glucose C6 H12 O6 was prepared by dissolving 0.465 moles of glucose in 2.20l…

A: Serial dilution

Q: Acconding to the eqution helow, whar ma of CaCl FW or CaC-110.s ) mut be added 255 of Agho rw of…

A: The given reaction is; 2 AgNO3 (aq) + CaCl2 (aq)→ 2 AgCl (s) + Ca(NO3)2 (aq) Given data; Given…

Q: Calculate the enthalpy change for the following reaction, given the known values below: Justify your…

Q: Fill in the missing chemical formulae in the tables below. base conjugate acid 2- HPO H,PO, H,0

Q: SCH3 OCH3 Br N(CH3)2 1 2 3 A) 3>1> 2>4 B) 3> 2>1>4 C) 4 > 2 > 3 >1 D) 1>3> 2 > 4

A: Order the carboxylic acid derivatives from most reactive to least reactive towards nucleophilic…

Q: OH EN MeCN

A: Here we have to synthesize the following given compounds from starting material methyl…

Q: Calculate the ΔH for the reaction: N2O4 + CO -> N2O + CO2. Show the complete and step by step…

A: Given reaction- N2O4+CO --> N2O+CO2

Q: A sample of oxygen gas at a pressure of 0.572 atm and a temperature of 21.8 °C, occupies a volume of…

Q: -1 A certain liquid X has a normal freezing point of 6.60 °C and a freezing point depression…

A: Given- Freezing point=6.60°C Kf=5.46°C Kg mol-1 Weight of NaCl=8.4g Weight of X=650g=0.650kg

Q: relative Ka pK a acid strength 9.6 (Choose one) :) A 5.52 (Choose one) : 10.796 (Choose one)

A: we need to complete the given table and fill the missing values

Q: kJ and its normal boiling point is 24. °C. Calculate the vapor pressure of X at-95. °C. The enthalpy…

Q: Draw the structures for the intermediates and product C, D, and E (only) in the following synthesis.…

A: Step 1 : LAH reduction of propinoyl chloride gives n-propanol. Step 2 : n-propanol is subjected to…

Q: Calculate the amount of heat needed to boil 97.5g of octane (C8H18), beginning from a temperature of…

Q: A solution contains 0.166 moles of an unknown compound in 300 g of benzene. The Kf of benzene is…

Q: An endothermic reaction has O a negative AH, gives off heat to the surroundings, and feels warm to…

A: There are two type of reactions on the basis of heat exhange i.e. Endothermic reaction Exothermic…

Q: What is the pH of a buffer that is 0.296 M HF and 0.416 M LiF? The K, for HF is 3.5 x 10-4. Your…

Q: what is the lbest mpound X o Give mechamism? to make Compound (9) oH (b) BY BY Br Nat

A: In this question we have to synthesis the compound X and also write its mechanism.

Q: Determine the number of atoms of O in 37.2 moles of Al2(CO3)3.

Q: Which of the following would be classified as a stron electrolyte? A. Benzoic acid B. Water C…

A: Strong Electrolyte: Is a solution which is completely dissociate in solution

Q: ion was found to E he reaction rate to fo

Q: What is the coordination of the cobalt ion in the compound: K[Co(ox)2CI(H2O)] ? А. 4-coordinate,…

A: Given-> K2[Co(ox)2Cl(H2O)]

Q: What daughter isotope is produced during the alpha decay of Uranium-238? Pu-242 Th-234 O Th-236…

A: ANS. Th-234

Q: Draw the products of each reaction. Please answer 1-3.

A: In this question we have to tell the products of the given reaction.

Q: Alkoxides R-O- can be used to synthesize alkenes as exemplified by the reaction shov below, where…

A: To calculate the value of rate constant , first we would determine rate law for this reaction using…

Q: An arctic weather balloon is filled with 12.6 L of helium gas inside a prep shed. The temperature…

Q: 1. LDA Br 2. 1-Phenylethanone

Q: Activity 3 Direction: Match the following processes with their descriptions. 1. Storage a. Some…

A: General chemistry

Q: What is the mass in grams of 3.86 x 1025 molecules of N2?

A: Mole concept :- 1 mole = 6.022×1023 (Avogadro's number) The mass of 6.022×1023 molecules of a…

Q: A student prepares a weak acid solution by dissolving 0.2400 g HZ to give 100. mL solution. The…

A: We have to predict the molar mass, effect on molar mass.

Q: If sea water contains 30 ppm gold, how many kilograms of sea water must be processed to remove 1.50…

Q: According to the following reaction, how much energy is evolved during the reaction of 32.5 g B2H6…

Q: Calculate the solubility at 25 °C of CaF, in pure water and in a 0.0110 MNAF solution. You'll find…

A: Given data,Molarity of NaF=0.0110 MKsp of CaF2=3.9×10-11Molar mass of CaF2=78.07 g/mol

Q: What is the pH of a 0.232 2M*C_{6}*H_{5}*C*O_{2}*HM solution if the K_{a} of C_{6}*H_{5}*C*O_{2}*H…

A: In this question we have to tell the PH of the solution.

Q: The rate at which a certain drug is eliminated by the body follows first-order kinetics, with a half…

Q: Calculate the amount of heat needed to boil 108. g of acetic acid (HCH,CO,), beginning from a…

A: Given data, Mass of acetic acid (m) = 108 g Begining temperature (T1) = 99.4 °C T1 = (99.4 + 273.15…

Q: Predict the products for the following reactions, indicate major and minor where applicable LOCH, 1)…

Q: Draw the structures for the intermediates and product C, D, and E (only) in the following synthesis.…

A: In this question we have to tell the product of the reaction.

Q: 4. H20 NHCOCH3 но. СООН SOCI2 HO, 5.

Q: Choose the correct cell potential. O Ecell = - 0.12 V O Ecell = + 0.09 V O Ecell = + 0.12 V %3D O…

Q: OEt `H HH ö:

A: We have reaction of epoxide and ester with water.

Q: For each titration, predict whether the equivalence point is less than, equal to, or greater than pH…

Q: Write the steps that complete the synthesis of this molecule.

Concept explainers

Ionic Equilibrium

Chemical equilibrium and ionic equilibrium are two major concepts in chemistry. Ionic equilibrium deals with the equilibrium involved in an ionization process while chemical equilibrium deals with the equilibrium during a chemical change. Ionic equilibrium is established between the ions and unionized species in a system. Understanding the concept of ionic equilibrium is very important to answer the questions related to certain chemical reactions in chemistry.

Arrhenius Acid

Arrhenius acid act as a good electrolyte as it dissociates to its respective ions in the aqueous solutions. Keeping it similar to the general acid properties, Arrhenius acid also neutralizes bases and turns litmus paper into red.

Bronsted Lowry Base In Inorganic Chemistry

Bronsted-Lowry base in inorganic chemistry is any chemical substance that can accept a proton from the other chemical substance it is reacting with.

Question

2262 Sat Aor 6
1 Which one of the following compounds is the strongest acid?
CNH2
-NH2
-CO2H
OH
CI-
СОН
CH
CH
C
A
B
2. Which one of the following amines will not produce an amide when mixed with an acid chloride?
NH
PHCH,NH2
PHNH2
Et,NH
A
C
3. What is the major product of the following sequence of reactions?
CH3 1) NBS, hv
(excess)
C(OH)3
CHO
CO2H
CH2O
2) NaOH, H20
(excess)
A
В
C
4. What is the major product of the following intramolecular aldol condensation reaction?
E
NaOH
H20
(dehydration)
A
C
3.
D.
B

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1 introduction

VIEW

Step 2 Reaction mechanism

VIEW

Step 3 Conclusion

VIEW

Step by step

Solved in 3 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Show how to synthesize the following amines from the indicated starting materials below. Each of the final products may require several sequential steps. Draw the structure for each of the steps and show the reagents required. Starting material Final product e) 5-methylhexan-2-one 1-amino-2,5-dimethylhexan-2-ol f) 1-iodopropane tetrapropylammonium iodide g) 4-ethyl-3-methylhexan-1-ol 3-ethyl-2-methylpentan-1-amine
Account for the following :(i) Primary amines (R-NH2) have higher boiling point than tertiary amines (R3N).(ii) Aniline does not undergo Friedel – Crafts reaction.(iii) (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Predict the products from the reactions of the following amines with sodium nitrite indilute HCl.N-ethylhexan-2-amine
Amide hydrolysis in basic conditions forms A. a carboxylic acid and an amine B. a carboxylate salt and an amine 3. an ester and an amine 4. a carboxylic acid and an amine salt
What amides would you react with LiAlH4 to form the following amines? a. benzylmethylamine c. diethylamine b. ethylamine d. triethylamine
Show how to synthesize the following amines from the indicated starting materials below. Each of the final products may require several sequential steps. Draw the structure for each of the steps and show the reagents required. Starting material Final product h) 4-ethyl-3-methylhexan-1-ol 4-ethyl-3-methylhexan-1-amine i) 2-phenylacetyl chloride N-N-dimethyl-2-phenylethan-1-amine j) ethyl acetate N-ethylpropan-2-amine
. Explain how you would rank the amines given below according to their basicity, together with the reasons.CH3NH2 (CH3)2NH (CH3)3N
Which of the following alcohols will give a carboxylic acid product when reacted with K2Cr2O7? 2-Butanol Methanol Tert-butyl-alcohol All of these will be oxidized to carboxylic acids. 2. Aromatic amines are _________ acidic, but stronger than the aliphatic amines are unique as they do not behave like any of the other amines neutral because of the polarity basic, but weaker than aliphatic amines 3. Which of the following is true of the Fischer esterification reactions? It is an equilibrium reaction that can never be driven far to the right. It proceeds until the limiting reagent is completely used up. It is an equilibrium reaction that can be driven to the right by the addition of water. It is an equilibrium reaction that can be driven to the right by the removal of water.
Define the simplest method to synthesize an amine ?
16-26 The p/fb of amphetamine is approximately 3.2 Amphetamine (a) Which form of amphetamine (the free base or its conjugate acid) would you expect to be present at pH 1.0, the pH of stomach acid? (b ) Which form of amphetamine would you expect to be present at pH 7.40, the pH of blood plasma?
The two most general amine syntheses are the reductive amination of carbonyl compounds and the reduction of amides.Show how these techniques can be used to accomplish the following syntheses.(a) benzoic acid S benzylamine (b) benzaldehyde S benzylamine(c) pyrrolidine S N@ethylpyrrolidine (d) cyclohexanone S N@cyclohexylpyrrolidine(e) HOOC¬(CH2)3 ¬COOH S pentane@1,5@diamine (cadaverine)
Which amine below is an primary aromatic amine? a. N-methyl-2-phenylethanamine b. All of the given c. 3-methylbenzamine d. N-ethylbenzamine