23. Baeyer Villager reactions are among the most useful of all rearrangement reaction. Ubserve the following reaction mechanism and select the correct statement(s). :OH :OH LOCOCF, OCOCF, R CF,CO,H By migration of Ph: By migration of R: R [A] [B] (A) If R = Me, yield (%) for [A] is maximum & major product [A] is formed (B) If R = t - Bu, yield (%) for [A] is maximum & major product [A] is formed (C) IER = Me, yield (%) for [B] is maximum & major product [B] is formed DIf R = t-Bu, yield (%) for [B] is maximum & major product [B] is formed

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter21: Nas: Nucleophilic Aromatic Substitution
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Paper-1_(Code-A)
2020
23.
Baeyer Villager reactions are among the most useful of all rearrangement reaction. Observe the following
reaction mechanism and select the correct statement(s).
:OH
:OH
LOCOCF,
OR To Go
OCOCF,
R CF.CO.H
R
By migration of Ph:
By migration of R:
R
[A]
[B]
A) If R = Me, yield (%) for [A] is maximum & major product [A] is formed
(B) If R = t - Bu, yield (%) for [A] is maximum & major product [A] is formed
(C) IFR = Me, yield (%) for [B] is maximum & major product [B] is formed
DIf R = t- Bu, yield (%) for [B] is maximum & major product [B] is formed
Transcribed Image Text:Paper-1_(Code-A) 2020 23. Baeyer Villager reactions are among the most useful of all rearrangement reaction. Observe the following reaction mechanism and select the correct statement(s). :OH :OH LOCOCF, OR To Go OCOCF, R CF.CO.H R By migration of Ph: By migration of R: R [A] [B] A) If R = Me, yield (%) for [A] is maximum & major product [A] is formed (B) If R = t - Bu, yield (%) for [A] is maximum & major product [A] is formed (C) IFR = Me, yield (%) for [B] is maximum & major product [B] is formed DIf R = t- Bu, yield (%) for [B] is maximum & major product [B] is formed
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