23. Baeyer Villager reactions are among the most useful of all rearrangement reaction. Ubserve the following reaction mechanism and select the correct statement(s). :OH :OH LOCOCF, OCOCF, R CF,CO,H By migration of Ph: By migration of R: R [A] [B] (A) If R = Me, yield (%) for [A] is maximum & major product [A] is formed (B) If R = t - Bu, yield (%) for [A] is maximum & major product [A] is formed (C) IER = Me, yield (%) for [B] is maximum & major product [B] is formed DIf R = t-Bu, yield (%) for [B] is maximum & major product [B] is formed
23. Baeyer Villager reactions are among the most useful of all rearrangement reaction. Ubserve the following reaction mechanism and select the correct statement(s). :OH :OH LOCOCF, OCOCF, R CF,CO,H By migration of Ph: By migration of R: R [A] [B] (A) If R = Me, yield (%) for [A] is maximum & major product [A] is formed (B) If R = t - Bu, yield (%) for [A] is maximum & major product [A] is formed (C) IER = Me, yield (%) for [B] is maximum & major product [B] is formed DIf R = t-Bu, yield (%) for [B] is maximum & major product [B] is formed
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter21: Nas: Nucleophilic Aromatic Substitution
Section: Chapter Questions
Problem 21CTQ
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