2C: C3H₁2O 100 80 60 48 28 e 4000 4.0 2H 3500 3.5 SECE 6962062 3000 3.0 2862 1H 2500 2.5 2.0 2000 2H N Experiment 2: NMR Spectroscopy 1468 1580 4H 6LET 1.0 1855 3H 1000 0.5 PPM

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL4: Proton (1h) Nmr Spectroscopy
Section: Chapter Questions
Problem 15E
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2C: C5H12O
100
80
60
40-
20-
0
4000
2H
3500
3.5
3335
3000
3.0
1H
2500
2.5
2.0
2000
2H
Experiment 2: NMR Spectroscopy
1.5
1468-
1500
4H
6LET
1.0
1968
1055
1000
TT
0.5 PPM
Transcribed Image Text:2C: C5H12O 100 80 60 40- 20- 0 4000 2H 3500 3.5 3335 3000 3.0 1H 2500 2.5 2.0 2000 2H Experiment 2: NMR Spectroscopy 1.5 1468- 1500 4H 6LET 1.0 1968 1055 1000 TT 0.5 PPM
For each problem, you must:
1) Calculate the degree of unsaturation.
2) Assign the principal IR absorption bands above 1500 cm¹
3) Draw the structure of the compound
4) Label the protons on your structure with letters and assign them to peaks on the NMR spectrum
(see the example below).
B
OHD
D
1H
C
2H
3.5
3.0
2.5
2.0
B
2H
1.5
A
3H
1.0 PPM
0.5
Transcribed Image Text:For each problem, you must: 1) Calculate the degree of unsaturation. 2) Assign the principal IR absorption bands above 1500 cm¹ 3) Draw the structure of the compound 4) Label the protons on your structure with letters and assign them to peaks on the NMR spectrum (see the example below). B OHD D 1H C 2H 3.5 3.0 2.5 2.0 B 2H 1.5 A 3H 1.0 PPM 0.5
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