3) In a tower 2 components, named as A and B, are present. The components are mutually present both in the gas and liquid phases. Component A, which is the solute, diffuses from the gas phase to the liquid phase. Component B, on the other hand, is the non-diffusing stagnant component. At a certain location in the tower, the bulk concentration of A in the gas phase is 45% by mole; and the bulk concentration of A in the liquid phase is 5% by mole. The film mass-transfer coefficients in the gas phase and the liquid phase are calculated as 1.465 x 10 kg mol A/s.m2.mol frac. and 1.967 x 10 kg mol A/s.m2.mol frac., respectively. Considering the given information, please calculate the interface concentration and the flux of A by using both liquid and gas phase equations. YA 0.00 0.02 0.05 0.09 0.13 0.18 0.25 0.37 0.53 0.72 XA 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45

EBK A SMALL SCALE APPROACH TO ORGANIC L
4th Edition
ISBN:9781305446021
Author:Lampman
Publisher:Lampman
Chapter93: Refractometry
Section: Chapter Questions
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1)
A liquid mixture involving ethanol and urea has a temperature of 285 K and film thickness of 2 mm.
This mixture is brought to contact with an organic liquid. After waiting for the system to reach equilibrium, the
urea concentrations in both sides of the contact interface were measured. The equilibrium bulk concentration
of urea in ethanol-urea mixture was recorded to be 3% by weight. Moreover, the equilibrium bulk concentration
of urea at the other side of the film was seen to be is 15% by weight. After the contact of the phases, the density
of the ethanol-urea mixture was found to be 961.7 kg/m, whereas at the other side of the film the density of
the urea-ethanol mixture was found to be 991.7 kg/m?. It is known that ethanol and the organic liquid are not
soluble in each other. Regarding the given information, what is the flux?
2)
A capillary has a diameter of 15 um and a length of 0.25 m. In an open system, a gaseous mixture
containing hydrogen (A) and nitrogen (B), having a temperature of 358 K is being diffused in the aforementioned
capillary. The mole fractions are at a constant value of xAI = 1.0 and xa2 = 0. Accordingly, for both nitrogen and
hydrogen gases, what is the Knudsen diffusivity values if the pressures are given as 0.005, 0.5 and 50 atm. Then
calculate the flux with the aforementioned pressures. (R can be used as 82.057x10 m2.atm/kgmol.K)
3)
In a tower 2 components, named as A and B, are present. The components are mutually present both
in the gas and liquid phases. Component A, which is the solute, diffuses from the gas phase to the liquid phase.
Component B, on the other hand, is the non-diffusing stagnant component. At a certain location in the tower,
the bulk concentration of A in the gas phase is 45% by mole; and the bulk concentration of A in the liquid phase
is 5% by mole. The film mass-transfer coefficients in the gas phase and the liquid phase are calculated as 1.465 x
10 kg mol A/s.m2.mol frac. and 1.967 x 10 kg mol A/s.m².mol frac., respectively. Considering the given
information, please calculate the interface concentration and the flux of A by using both liquid and gas phase
equations.
YA
0.00
0.02
0.05
0.09
0.13
0.18
0.25
0.37
0.53
0.72
XA
0.00
0.05
0.10
0.15
0.20
0.25
0.30
0.35
0.40
0.45
Transcribed Image Text:1) A liquid mixture involving ethanol and urea has a temperature of 285 K and film thickness of 2 mm. This mixture is brought to contact with an organic liquid. After waiting for the system to reach equilibrium, the urea concentrations in both sides of the contact interface were measured. The equilibrium bulk concentration of urea in ethanol-urea mixture was recorded to be 3% by weight. Moreover, the equilibrium bulk concentration of urea at the other side of the film was seen to be is 15% by weight. After the contact of the phases, the density of the ethanol-urea mixture was found to be 961.7 kg/m, whereas at the other side of the film the density of the urea-ethanol mixture was found to be 991.7 kg/m?. It is known that ethanol and the organic liquid are not soluble in each other. Regarding the given information, what is the flux? 2) A capillary has a diameter of 15 um and a length of 0.25 m. In an open system, a gaseous mixture containing hydrogen (A) and nitrogen (B), having a temperature of 358 K is being diffused in the aforementioned capillary. The mole fractions are at a constant value of xAI = 1.0 and xa2 = 0. Accordingly, for both nitrogen and hydrogen gases, what is the Knudsen diffusivity values if the pressures are given as 0.005, 0.5 and 50 atm. Then calculate the flux with the aforementioned pressures. (R can be used as 82.057x10 m2.atm/kgmol.K) 3) In a tower 2 components, named as A and B, are present. The components are mutually present both in the gas and liquid phases. Component A, which is the solute, diffuses from the gas phase to the liquid phase. Component B, on the other hand, is the non-diffusing stagnant component. At a certain location in the tower, the bulk concentration of A in the gas phase is 45% by mole; and the bulk concentration of A in the liquid phase is 5% by mole. The film mass-transfer coefficients in the gas phase and the liquid phase are calculated as 1.465 x 10 kg mol A/s.m2.mol frac. and 1.967 x 10 kg mol A/s.m².mol frac., respectively. Considering the given information, please calculate the interface concentration and the flux of A by using both liquid and gas phase equations. YA 0.00 0.02 0.05 0.09 0.13 0.18 0.25 0.37 0.53 0.72 XA 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45
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