(3) The rate constants for the exchange reaction: [Cr(H2O)sX]? + [*Cr(H2O)6]?[*Cr(H2O)sX] + [Cr(H2O)6]? where *Cr is 5!Cr, a radioactive nuclide and X is a mono-anionic ligand, are given in the table. Outline the likely mechanism and explain the difference in the rate constants. F CI Br N3 k (mol1 dm s) 1.2 x 10-3 11 60 >1.2

(3) The rate constants for the exchange reaction: [Cr(H2O)sX]? + [Cr(H2O)6]?[Cr(H2O)sX] + [Cr(H2O)6]? where *Cr is 5!Cr, a radioactive nuclide and X is a mono-anionic ligand, are given in the table. Outline the likely mechanism and explain the difference in the rate constants. F CI Br N3 k (mol1 dm s) 1.2 x 10-3 11 60 >1.2

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section: Chapter Questions

Problem 125QRT: Two different compounds are known with the formula Pd(py)2Cl2, but there is only one compound with...

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