What is the LFSE for the [Re(H2O)6]3+complex, knowing that ΔΔo =  33000 cm-1 and P= 15000 cm-1 ?

Q: Write all possible photochemical processes of [Cr(bipy)3]C13 complex after irradiation with 350 nm…

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Q: Consider the Tanabe - Sugano diagram for [V(H20)6]²+ octahedral complexes shown below 1. What is the…

A: The most stable electronic arrangement is of lowest energy and is ground state electronic…

Q: (d) [Cr(OH)2]¿* ions are pale blue-green but chromate (Cr,O,) ion is an intense yellow in colour.…

A: Ans: [Cr(H2O)6]3+ is pale green beacuse in this complex Cr has +3 oxidation state with d3…

Q: In 2001, chemists at SUNY-Stony Brook succeeded in syn-thesizing the complex trans-[Fe(CN)4(CO)2]2-,…

A: The compounds where metal ion is the central metal and molecules that can share their electron with…

Q: 580 nm, which is the wavelength of its maximum absorption the complex Fe(SCN)2+ has a molar…

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Q: Me3P-M ligand is a pi acceptor or pi donor?

A: A ligand can act as a pi donor or pi acceptor based on the fact that a pi donor ligand will have…

Q: Write down the IUPAC names of the following complexes and also give stereochemistry and magnetic…

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Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? a.…

A: This question is related to coordination Chemistry. Coordination complexes are the molecules in…

Q: [FeF6]3− is almost colourless whereas [CoF6]3− is coloured (and has only 1 band in the visible…

A: The electron of metal in the complex is normally excited to a higher energy level if the light falls…

Q: 2. Which of the two complexes examined in this experiment, Co(H20)6²* (pink) and CoClą2- (blue), is…

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Q: Three absorption bands were observed at 11200, 18350, 29000 cm-1 in the electronic spectrum of the…

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Q: By using valence bond theory and ligand field theory, prove that [Ru(OMe)2(PMe3)4] is a paramagnetic…

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Q: Bearing in mind the Jahn-Teller theorem, explain what type of distortion can be expected for [VCl,]³…

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Q: Q6.  a) which of these complexes [CoF6]3- and [Co(en)3]3+ Is high spin and how many unpaired…

A: Therefore, [CoF6]3- is a high spin complex , and there are 4 unpaired Electrons present in it.

Q: Which among the following complexes has the highest value of spin magnetic moment?     a.…

A: Spin magnetic moment (s) = √(n(n+2)) n = number of unpaired electron ->As unpaired electron…

Q: The magnetic moment of [Mn(NCS)6 ]4- is 6.06 μBM, is it high or low spin? why?

A: In this question, we will see that the complex is high spin or low spin and why. High spin complex…

Q: Jahn-Teller distortions are often encountered with а. octahedral complexes of dº and high o spin d4…

A: Jahn teller distortion occurs in those complexes which has unpaired electron in t2g or eg orbital ie…

Q: Please help with this work. Derive the free-ion term (show the steps) and (b) find (ONLY) the ground…

A: This is multi part questions and as per answering guidelines I can only answer first 3 questions if…

Q: The rate of attack on [Co(H 2 O) 6 ]^ 3+ by an entering group Y is nearly independent of Y, with the…

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Q: For the high-spin Fe(II) ion, calculate the crystal field stabilisation energy as a function of…

A: The crystal field stabilisation energy for octahedral complexes is calculated as: CFSE = (-0.4 ×…

Q: The iron oxalate complex when dissolved in water gives a green coloured solution, using the colour…

A: Given A color wheel with distribution of colors and its complimentary colors.

Q: When compared to that of the free thiourea, the vibrational frequency of carbon-sulfur bond in…

A: Here we have to choose correct option for above questions

Q: When water ligands in [Ti(H2O)6]3+ are replaced by CN- ligands to give [Ti(CN)6]3-, the maximum…

A: [Ti(H2O)6]3+ is an octahedral complex and ligand H2O is a weak field ligand. [Ti(CN)6]3- is also an…

Q: Rank the following ions in the weak octahedral field in order of increasing Jahn-Teller effect.…

A: Hjsjsj

Q: For [Fe(CN)6]*, please write the valence electron configuration of the metal ion, the ground- state…

A: In the given complex, iron is the central metal atom which is present in +2 oxidation state. The…

Q: Q1 a) which of these complexes [CoFs]³-and [Co(en);]+ Is high spin and how many unpaired electron…

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Q: What kind of complex anion do you expect in: a) LiAl(SiO3)2 b) Na2Fe5Si8O22(OH)2 c) Ni3(Si2O5)(OH)4

A: The solution of the given question is-

Q: Explain by means of different mechanisms of stereochemical fluctuations, how cistrans-isomerization…

A: Let's discuss about the mechanism for cis-trans isomerisation in five coordinated transition metal…

Q: The d-electron count of the transition metal center for [((7-CSH3)Ir(CO)2(CH3)] and (Rh(PPH3),CI],…

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Q: What is the LFSE for the [Co(bipy)3]Cl2 complex, knowing that $\Delta$o =  11300 cm-1 and P= 22500…

A: LFSE is the ligand field stabilization energy. For the given complex, Co is in +2 state. A strong…

Q: Consider the following complexes: [FeCl6]3- and [Fe(CN)6]3-, which possess very different magnetic…

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Q: 4. The [Fe(H2O)6]3+ complex has a high spin configuration. The [Fe(CN)6]3- has 3 electronic…

A: According to rule of spin multiplicity , transition occurs between two states having same spin…

Q: Explain how many D-d transitions you would theoretically expect in complex ions [Ni(NH3)6]2+,…

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Q: The ligand-field-stabilization-energies (LFSE) of three pairs of [ML«]³" and [ML«J* complexes are…

A: For octahedral complexes: For a high spin complex the energy gap between t2g and eg is less but for…

Q: A first-row transition-metal complex of formula [M(H2O)6]²+ has a magnetic moment of 3.9 Bohr mag-…

A: Given: Magnetic moment = 3.9 B.M Complex is MH2O62+, here M is first-row transition metal

Q: Three absorption bands were observed at 11200, 18350, 29000 cm-1 in the electronic spectrum of the…

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Q: How many unpaired electrons would you expect for the complex [Co(NH;)5NO,]2+?

A: Given Complex is: [Co (NH 3)5 NO 2]2+ Let the oxidation state of Co be x So, So, Cobalt is in +4…

Q: a) Draw the lewis structure of the nitrate ion and discuss its potential to serve as an ambidentate…

A: Ambidentate Ligand : This are one type of monodentate ligands having two different donar atoms, that…

Q: 6. What are the differences between these complexes [Co(NH3)6]Cl3 , [Co(H20)6]Cl2, (Base your answer…

A: CFT is the concept of solid-state physics used to explain the properties of coordination complexes.…

Q: (b). (i). The electronic absorption spectrum of aqueous [Ti(OH2)6]?* (stable under acidic…

A: “Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: a) determine the oxidation state, d electronic configuration and spin-only magnetic moment of…

A: According to Q&A guidelines of Bartleby, we are supposed to answer only the first question out…

Q: There are three spin allowed transitions for [V(H2O)6]3+complex . According to the Tanabe-Sugano…

A: V1 corresponds to 3T1g to 3T2g  V2 corresponds to 3T1g to 3T1g (P) V3 corresponds to 3T1g to 3A2g…

Q: What are the possible magnetic moments of Co(II) in tetrahedral, octahedral, and square-planar…

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Q: What is the crystal field electron configuration of the [Mn(NCS)6]4- complex with a magnetic moment…

A: 1st Have to determine oxidation state of Mn. There are two options for a octahedral complex. High…

Q: Write all possible photochemical processes of [Cr(bipy)3]CI3 complex after irradiation with 350 nm…

A: The photochemical process of [Cr(bipy)3] complex after irradiation with 350 nm light to be…

Q: (b) Discuss the electric quadruple splitting in Mössbauer spectroscopy. Explain how this is helpful…

A: Answer - Quadrupole splitting - Quadrupole splitting is measured as the separation between these two…

Q: Question attached

A: Nephelauxetic effect When ligand approaches the metal ion, d-electron cloud of metal ion expands…

Q: An acid solution of [Co(NH3)6]3+ replaces one amine ligand ~1013 times faster when radiated with…

A: Solutions An acid solution of [Co(NH3)6]3+ replaces one amine ligand ~1013 times faster when…

Q: What is the ligand field stabilization energy for a high spin d6 complex in terms of Δ0?

A: Ligand field stabilization energy(LFSC) is also called as crystal field stabilization energy (CFSC).…

Q: For  [Co(H2O)6]2+ , Discuss the similarities/dissimilarities in the magnetic moment values with…

A: In a chemical species magnetic behavior comes from its spin of the unpaired electrons(spin angular…

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.