3. (8 points) Provide the IUPAC nomenclature of the following compounds, including their relative or absolute stereochemistry where applicable: a) H CH3 Name: b) Name: Et Name: d) (do not assign R/S below) Name: CH3 CH₂
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- In some nucleophilic substitutions under SN1 conditions, complete racemization does not occur and a small excess of one enantiomer ispresent. For example, treatment of optically pure 1-bromo-1phenylpropane with water forms 1-phenylpropan-1-ol. (a) Calculate how much of each enantiomer is present using the given optical rotation data. (b) Which product predominates—the product of inversion or the product of retention of configuration? (c) Suggest an explanation for this phenomenon.In some nucleophilic substitutions under SN1 conditions, complete racemization does not occur and a small excess of one enantiomer is present. For example, treatment of optically pure 1-bromo-1-phenylpropane with water forms 1- phenylpropan-1-ol. (a) Calculate how much of each enantiomer is present using the given optical rotation data. (b) Whichproduct predominates—the product of inversion or the product of retention of conguration? (c) Suggest an explanation for this phenomenon.In some nucleophilic substitutions under SN1 conditions, completeracemization does not occur and a small excess of one enantiomer ispresent. For example, treatment of optically pure 1-bromo-1-phenylpropane with water forms 1-phenylpropan-1-ol. (a) Calculate how much of each enantiomer is present using the given optical rotation data.(b) Which product predominates—the product of inversion or the product of retention of configuration? (c) Suggest an explanation for this phenomenon.
- Addition of HCl to alkene X forms two alkyl halides Y and Z. (A) Label Y and Z as a kinetic or thermodynamic product and explain why. (B) Explain why the addition of HCl occurs at the exocyclic C=C, rather than the other C=CFor the following molecule: A. Draw both chair conformations and label substitutents as axial or equatorial B. Indicate which conformation is more stable using equilibrium arrows C. Predict the major product of the reaction with sodium methoxide D. Predict the major product of the reaction with potassium tert-butoxideIn some nucleophilic substitutions under SN1 conditions, complete racemization does not occur and a small excess of one enantiomer is present. For example, treatment of optically pure 1-bromo-1-phenylpropane with water forms 1-phenylpropan-1-ol. (a) Calculate how much of each enantiomer is present using the given optical rotation data. (b) Which product predominates—the product of inversion or the product of retention of configuration? (c) Suggest an explanation for this phenomenon.
- what is degree unstaturation of the following ? and draw 2 structures per each number8. The anti-formation of (5)-3-phenyl-2-butanone is included. Draw the attack produce of NaBHa by the face if of this conformation.For each of the following: I) draw the structures of all product(s), both constitutional and stereoisomers; ii.) Indicate the stereocenters with and asterisk;
