3. Consider borane, BH3.a) To what point group does it belong?b) Construct a transformation table for the 1s orbitals on the three hydrogens and determine thesymmetry adapted linear combinations for these orbitals.

Answered: Image /qna-images/answer/e12c581f-c3da-41eb-a9f4-3cd97a8a6bf4.jpg

3. Consider borane, BH3. a) To what point group does it belong? b) Construct a transformation table for the Is orbitals on the three hydrogens and determine the symmetry adapted linear combinations for these orbitals.

3. Consider borane, BH3. a) To what point group does it belong? b) Construct a transformation table for the Is orbitals on the three hydrogens and determine the symmetry adapted linear combinations for these orbitals.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter13: Introduction To Symmetry In Quantum Mechanics

Section: Chapter Questions

Problem 13.27E: Determine the point group of the following molecules. a cis1,2 Dichloroethylene b trans1,2...

See similar textbooks

Related questions

Q: Consider the cis-1,3-butadiene that has a C2v point group (structure is shown below). Using LCAO-MO…

Q: Determine the point group of the molecule shown. Make OS sure to rotate the molecule to see all of…

A: SF6 comes into the special category of molecules. It has regular octahedral geometry. Molecules with…

Q: (i) What is the basis of C versus D point group classification?

Q: Determine the point group of the molecule shown. The answer should have the correct formatting for…

Q: To what point group does CCIa belong? Using the appropriate character table, construct a reducible…

Q: Verify the point groups of the following molecule : F2

A: Point group basically depicts the 3D arrangement of a molecule using symmetry elements, such as axis…

Q: In a C2h point group, the character table lists the dxz and dyz orbitals in the Bg character. Do…

A: The resemblance of one part of the molecule exactly to another part of the molecule is known as a…

Q: Determine the point group for dichloro(phenyl)phosphine. Please see photo attached.

A: Point group of dichloro(phenyl) phosphine is

Q: (b) Work out the point group of- (i) CIF;; (ü) IF5.

Q: Determine the point groups for H -C = C - F.

A: The structure of the given compound is linear and its molecular formula is C2HF. Functional group in…

Q: Water belongs to the C2v point group with the symmetry elements shown below: Ov Ov, C2 Along with…

A: If the product of any two elements must be on the group, then this group is called closed group.…

Q: Draw a pz and a dz2 orbital and assign their point groups

A: Px is symmetrical and dz2 is symmetrical

Q: Assign (i) cis-dichloroethene and (ii) trans-dichloroethene to point groups.

A: Before assigning the point group determine the symmetry operations which are operative in the…

Q: Determine the point group of the molecule shown. Be sure O B OF to rotate the molecule so that you…

Q: Q2 C2v? What is the point group resulting from adding the inversion operation to

Q: 3. Determine the multiplication table for the D2h point group.

A: Multiplication table: for any molecule as a group all the symmetry operations can be written in the…

Q: Determine the point group of the following orbital:

A: The given orbital is f0 orbital

Q: 1. Consider cyclobutadiene molecule (structure is shown below) has a point group Da. Using LCAO-MO…

A: ANSWER :

Q: The molecule of interest PtCl4^2-. Find the irreducible representation(s) of the pz orbitals, using…

A: The point group of tetrachloroplatinate is D4h.The reducible representation of s and p orbitals are…

Q: Answer all questions in terms of the ammonia molecule (NH3). homenud a. What point group does NH3…

A: We have to predict the point group of ammonia.

Q: Determine the point group of the molecule shown. Your answer should have the correct formatting for…

A: The given molecule p-xylene contains following symmetry elements. Three, two fold rotational axis…

Q: Using models, determine the point group for each of the following molecules. If a sketch is not…

A: The point groups are as shown below:

Q: Determine the point group of the molecule. Be sure to rotate the molecule so that you can see all of…

A: A point group is a chemical notation or a representation which tells us about the symmetry elements…

Q: 2- 2-

A: Point group of a compound depends on the symmetry elements present in it.

Q: point groups and symmetry elements

Q: 4. List ALL of the symmetry operations for each of the following compounds then assign a point group…

A: Answer 4 : Point group of a, b & c compound = ? Note : As per our company guidelines, we are…

Q: 3. For Dan, use sketches of the orbitals to show that d., have B2g symmetry i.e. show how the…

A: D4h is a point group with the symmetry elements - E, σh , 4σv , C4, 4C2 D4h have 1 horizontal…

Q: Given thee set of operations [E, C4, sigma h], determine the other operations that must be present…

Q: Determine me point group of the following objelt and form me 1. group multiphication bable.

A: To find out the symmetry group of the given of the object.

Q: Determine the point group of the molecule. Be sure to rotate the molecule so that you can see all of…

Q: (b) Work out the point group of (i) CIF;; (ü) IF5.

A: To determine point group of a molecule , we first calculate the symmetry elements present in the 3D…

Q: Molecule: [W(CN)8] 2- . Point Groupd D4h. Use the CN bond vectors as your basis to determine a…

A: Individual species are orthogonal to each other and the consequences of general theory of group…

Q: 4 Considering the carbonate atomic (CO32- ) construct the SALCS. 1) Make a table that has each…

A: Solution- the carbonate atomic (CO32- ) construct the SALCS. 1) We have to make a table that has…

Q: Identify and Draw the operations, the symmetry elements and how the atoms in the BF3 molecule are…

A: Symmetry operations and symmetry elements are two basic concepts in group theory. On performing an…

Q: 1. A fellow student claims that there is one more irreducible representation for the Can point…

A: The solution of the question is given below:

Q: Draw a pz and a d orbital and assign their point groups.

A: Pz is unsymmetrical in phase but dz2 is symmetrical.

Q: 1. Work out the symmetry point group of the following (any two). (i) S,0, (ii) allene (iii) IFs

A: This Question is based upon group theory. According to question any two point group has to be given.

Q: Define 'similarity transformation'. Taking the case of a C3, point group, show that =

Q: 17. Determine point group for next molecules Methane Hydrazine

A: Depending on the symmetry elements, the point group is determined. The common symmetry operations…

Q: (4) Determine the point group of CHa and show the symmetry elements/operations using 3D drawing. (5)…

A: In point group classification we have to find out different axis of rotation,plane of rotation ,if…

Q: (b) Work out all the associated symmetry operations that can be generated from S3.

Q: [CHS] + is in the Cs point group: Draw the reducible representation of the 5 hydrogens Character…

A: This point group contains only two symmetry operations: E the identity operation, σ a mirror plane.…

Q: 3. Throughout the course we will need to determine/know the symmetries of various orbitals.…

Q: O.

A: Pont group comes from the mathematical treatment to a molecule . By the point group we can explain…

Q: Determine the point group of the molecule shown. Be sure to rotate the molecule so that you can see…

Q: 2. Consider 1,3-cyclobutadiene, and answer the following: a) To what point group does it belong?

A: "Since there are multiple sub-parts in this question and it is not mentioned that which one has to…

Q: (c) Using POC13 as an example, develop the reducible representation of its point group.

A: •A reducible representation can be defined as the representation of higher dimension which can be…

Q: Determine the point group of the molecule shown. Be sure to rotate the molecule so that you can see…

A: A point group is a chemical notation or a representation which tells us about the symmetry elements…

Question

3. Consider borane, BH3.
a) To what point group does it belong?
b) Construct a transformation table for the 1s orbitals on the three hydrogens and determine the
symmetry adapted linear combinations for these orbitals.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Determine the point groups of the following molecules. a Fe(CO)5, which has a trigonal bipyramidal structure, b CO32, which has three resonance structures that contribute to its overall shape, c The perfectly staggered conformation of ethane, d The perfectly eclipsed conformer of ethane.
In which point group are the letters A, F, N respectively? a) C2v, C2v, D2h b) C2v, C2v, C2v c) C2v, Cs, C2h d) C2v, D2h, Cs
What do you expect the structure of Ge2H4 to look like ? sketch the structure in a clear three dimensional representation and give it's point group.
Determine the point groups for H -C = C - F.
Make sketches of the following showing approximately correct geometry and all valence shell electrons. Identify all symmetry elements present and determine the point group for the species (d) SO32-. (e)SF6 (f) IF5 (g) CIF3 (h) SO3 (i) CIO2- j) NSF this is the next sub part, A B and C is already answered.
1. Find the point groups of the following shapes, interpreting (a) as a square and (b)-(p) as derivatives with lines perpendi
Consider the octahedral species CrCl63- (point group Oh). What point group results by (a) removing one Cl (b) replacing one Cl with one Br (c) removing two trans Cl’s
Determine the point groups for H -C = C - CH3.
Please help Orbital and SALC symmetry Methane CH4 --- Point group = Td E, 8C3, 3C2, 6S4, 6σd I. What are the symmetries of the relevant orbital on C? II. What are the symmetries of the SALCs generated from the hydrogen orbitals? III. Use parts I and II to draw an MO diagram for CH4 IV. Use your MO diagram to sketch your prediction of the photoelectron spectrum for CH4
Please help me Point group of square Antiprismatic is D4d
what is the point group of BeF3-
Verify the point groups of the following molecule : F2