3. There is a class of polyesters that have the general structure shown below. . For example, in polyethylene terephthalate (PET) m =1. How would you expect the Tg ad Tm of these polymers to vary with m, given that the molecular weight of the chain is held constant? Give reasons for your answer. Also, assuming that you are now just considering one member of this class of polymers, say PET, how does the Tg vary with molecular weight, n.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.34P
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3. There is a class of polyesters that have the general structure
shown below. .
For example, in polyethylene terephthalate (PET) m =1.
How would you expect the Tg ad Tm of these polymers to
vary with m, given that the molecular weight of the chain is
held constant? Give reasons for your answer. Also,
assuming that you are now just considering one member of
this class of polymers, say PET, how does the Tg vary with
molecular weight, n.
Transcribed Image Text:3. There is a class of polyesters that have the general structure shown below. . For example, in polyethylene terephthalate (PET) m =1. How would you expect the Tg ad Tm of these polymers to vary with m, given that the molecular weight of the chain is held constant? Give reasons for your answer. Also, assuming that you are now just considering one member of this class of polymers, say PET, how does the Tg vary with molecular weight, n.
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