The red line shows the average total charge on each molecule in solution (right axis), while the green, blue and yellow lines show the fraction of ea of three differently ionized forms of 1b ) draw the structure of the green,red,yellow line and give the forma charge of each line i) From the graph estimate the isoelectric point of 1b and explain ho you arrived at your results? ii) Estimate the pk of the carboxylic acid group (-COOH) and ammonium group (-NH3*) in 1b and explain how you arrived at your result?

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The red line shows the average total charge on each molecule in solution
(right axis), while the green, blue and yellow lines show the fraction of each
of three differently ionized forms of 1b
i) draw the structure of the green,red, yellow line and give the formal
charge of each line
ii) From the graph estimate the isoelectric point of 1b and explain how
you arrived at your results?
iii) Estimate the pk of the carboxylic acid group (-COOH) and
ammonium group (-NH3*) in 1b and explain how you arrived at your
result?
Fraction of species
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
18
0.0
2.0
4.0
6.0
nH
8.0
10.0
12.0
1.0
0.8
0.6
0.4
0.2
0.0
-0.2
-0.4
-0.6
-0.8
-1.0
14.0
Total Charge
Transcribed Image Text:The red line shows the average total charge on each molecule in solution (right axis), while the green, blue and yellow lines show the fraction of each of three differently ionized forms of 1b i) draw the structure of the green,red, yellow line and give the formal charge of each line ii) From the graph estimate the isoelectric point of 1b and explain how you arrived at your results? iii) Estimate the pk of the carboxylic acid group (-COOH) and ammonium group (-NH3*) in 1b and explain how you arrived at your result? Fraction of species 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 18 0.0 2.0 4.0 6.0 nH 8.0 10.0 12.0 1.0 0.8 0.6 0.4 0.2 0.0 -0.2 -0.4 -0.6 -0.8 -1.0 14.0 Total Charge
1.0
Fraction of species
DSC
6.0
PH
ОН
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.0
H₂N
2.0
4.0
О
8.0
10.0
ОН
12.0
10
14.0
1.0
0.8
0.6
0.4
0.2
0.0
-0.2
-0.4
-0.6
-0.8
-1.0
Total Charge
Transcribed Image Text:1.0 Fraction of species DSC 6.0 PH ОН 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0.0 H₂N 2.0 4.0 О 8.0 10.0 ОН 12.0 10 14.0 1.0 0.8 0.6 0.4 0.2 0.0 -0.2 -0.4 -0.6 -0.8 -1.0 Total Charge
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