3.1. Give the products that would be expected to be formed under the specifiedreaction conditions. Be sure to specify all aspects of the stereochemistry.(a)CH₂CH₂(c)HOCH₂(1)(S)-CH₂(CH₂)₂CHCH₂ + C₂H₁(k)CH₂OOH11N(CPH)2PhCO, O,CPhC₂HsCH₂O(CH)₂CHBr +OCH₂HCH,CO,HHCICH₂OH-(PhO),PCH, FDMF, 20°C10 minC₂H₁₂O₂ClBB₂, -78°C0°C, 1 hCH₂Cl₂(OCH3)3Et₂NEN*CrC38H28N5O,11) NaOH2) H*NCH₂CH heatCH₁3ClC₁1H₁20248% HBr(b)C₁7H₁7NO₂CHJ(CH,),CH,OH + CICH,OCH,(d)C₂H₂O₂CCH₂CHCO₂C₂H₁OH(1)CH₂CHCH₂OH(h)(₁)C₁3H₁3PO3CH₂(1)PhCO, CHHOCH₂HOCH₂HPPh₂CC14C₂H₂O₂CH1) p-toluenesulfonyl chlorideOH2) PhS™ Na*1) Ph₂P, HN₂2) DEADC10H₁7CICO₂H'H1) CH₂SO₂CIpyridineEIN(+Pr)₂CH₂Cl₂2) Na SHMPA+- BuOHDCC,DMAPC₂H₁3N₂O4C16H18SC₂H1802C14H12O₂SC10H1604

Answered: Image /qna-images/answer/19b7abcb-ff19-4292-9844-e0da1b1cf684.jpg

3.1. Give the products that would be expected to be formed under the specified reaction conditions. Be sure to specify all aspects of the stereochemistry. (a) CH₂CH₂ HCI CH₂OH C,H₁₂O₂Cl (b) CH₂(CH₂) CH₂OH + CICH₂OCH, EtN(/Pr)₂ CH₂Cl₂ C₂H₁80₂

3.1. Give the products that would be expected to be formed under the specified reaction conditions. Be sure to specify all aspects of the stereochemistry. (a) CH₂CH₂ HCI CH₂OH C,H₁₂O₂Cl (b) CH₂(CH₂) CH₂OH + CICH₂OCH, EtN(/Pr)₂ CH₂Cl₂ C₂H₁80₂

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter15: Radical Reactions

Section: Chapter Questions

Problem 11E

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Question

3.1. Give the products that would be expected to be formed under the specified
reaction conditions. Be sure to specify all aspects of the stereochemistry.
(a)
CH₂CH₂
(c)
HOCH₂
(1)
(S)-CH₂(CH₂)₂CHCH₂ + C₂H₁
(k)
CH₂O
OH
11
N(CPH)2
PhCO, O,CPh
C₂Hs
CH₂O
(CH)₂CHBr +
OCH₂
H
CH,CO,H
HCI
CH₂OH
-
(PhO),PCH, F
DMF, 20°C
10 min
C₂H₁₂O₂Cl
BB₂, -78°C
0°C, 1 h
CH₂Cl₂
(OCH3)3
Et₂N
EN*Cr
C38H28N5O,1
1) NaOH
2) H*
NCH₂CH heat
CH₁3Cl
C₁1H₁202
48% HBr
(b)
C₁7H₁7NO₂
CHJ(CH,),CH,OH + CICH,OCH,
(d)
C₂H₂O₂CCH₂CHCO₂C₂H₁
OH
(1)
CH₂CHCH₂OH
(h)
(₁)
C₁3H₁3PO3
CH₂
(1)
Ph
CO, CH
HOCH₂
HOCH₂
H
PPh₂
CC14
C₂H₂O₂C
H1) p-toluenesulfonyl chloride
OH
2) PhS™ Na*
1) Ph₂P, HN₂
2) DEAD
C10H₁7CI
CO₂H
'H
1) CH₂SO₂CI
pyridine
EIN(+Pr)₂
CH₂Cl₂
2) Na S
HMPA
+- BuOH
DCC,
DMAP
C₂H₁3N₂O4
C16H18S
C₂H1802
C14H12O₂S
C10H1604

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