37. What will be the major product of the reaction of 1 mol of propyne with each of the following reagents? a. HBr (1 mol) b. HBr (2 mol) c. Br2 (1 mol)/CH2C12 d. Br2 (2 mol)/CH,Cl2 e. aqueous H2SO4, H9SO4 f. borane in THF followed by j. sodium amide k. product of part j followed by 1-chloropropane H2O2/HO /H2O g. excess H,, Pd/C h. H2/Lindlar catalyst i. sodium in liquid ammonia at -78 °C

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter7: Alkynes
Section: Chapter Questions
Problem 7.35P
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37. What will be the major product of the reaction of 1 mol of propyne with each of the following reagents?
a. HBr (1 mol)
b. HBr (2 mol)
c. Br2 (1 mol)/CH,Cl2
d. Br2 (2 mol)/CH2C12
e. aqueous H2SO4, HgSO4
f. borane in THF followed by
H,O2/HO¯/H2O
g. excess H2, Pd/C
h. H,/Lindlar catalyst
i. sodium in liquid ammonia at -78 °C
j. sodium amide
k. product of part j followed by
1-chloropropane
Transcribed Image Text:37. What will be the major product of the reaction of 1 mol of propyne with each of the following reagents? a. HBr (1 mol) b. HBr (2 mol) c. Br2 (1 mol)/CH,Cl2 d. Br2 (2 mol)/CH2C12 e. aqueous H2SO4, HgSO4 f. borane in THF followed by H,O2/HO¯/H2O g. excess H2, Pd/C h. H,/Lindlar catalyst i. sodium in liquid ammonia at -78 °C j. sodium amide k. product of part j followed by 1-chloropropane
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