4) The equilibrium constant for the reaction Ag*(aq) + 2NH3(aq)= Ag(NH3)2*(aq) is K= 1.7 x 107 at 25°C. What is AG° at this temperature?

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter19: Principles Of Chemical Reactivity: Electron Transfer Reactions
Section19.6: Electrochemistry And Thermodynamics
Problem 19.9CYU: Calculate the equilibrium constant at 25 C for the reaction 2 Ag+(aq) + Hg() 2 Ag(s) + Hg2+(aq)
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4) The equilibrium constant for the reaction
Ag*(aq)+ 2NH3(aq)= Ag(NH3)2*(aq)
is K= 1.7 × 107 at 25°C. What is AG° at this temperature?
Transcribed Image Text:4) The equilibrium constant for the reaction Ag*(aq)+ 2NH3(aq)= Ag(NH3)2*(aq) is K= 1.7 × 107 at 25°C. What is AG° at this temperature?
5) Iron(III) oxide can be reduced by carbon monoxide.
Fe2O3(s) + 3CO(g)=2Fe(s) + 3CO2(g)
Use the following thermodynamic data at 298 K to determine the equilibrium constant at
this temperature.
Substance:
Fe,O3(s)
CO(g)
Fe(s)
CO:(g)
AH°: (kJ/mol):
-824.2
-110.5
-393.5
AG°; (kJ/mol):-742.2
-137.2
-394.4
S°(J/K • mol):
87.4
197.7
27.78
213.7
Transcribed Image Text:5) Iron(III) oxide can be reduced by carbon monoxide. Fe2O3(s) + 3CO(g)=2Fe(s) + 3CO2(g) Use the following thermodynamic data at 298 K to determine the equilibrium constant at this temperature. Substance: Fe,O3(s) CO(g) Fe(s) CO:(g) AH°: (kJ/mol): -824.2 -110.5 -393.5 AG°; (kJ/mol):-742.2 -137.2 -394.4 S°(J/K • mol): 87.4 197.7 27.78 213.7
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