Calcium carbonate undergoes thermal decomposition CaCO3(s) ⇌ CaO(s) + CO2(g) at high temperatures. The equilibrium constant for the reaction is 0.0120 at 900 K. Calculate the partial pressure of carbon dioxide, CO2, when calcium carbonate, CaCO3, is heated at 900 K. 2. Calculate the standard cell potential for the reaction Zn(s)|Zn^2+(aq)||MnO^4-(aq), Mn^2+(aq), H+(aq)|Pt(s) 3.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter16: Thermodynamics: Directionality Of Chemical Reactions
Section: Chapter Questions
Problem 91QRT: Actually, the carbon in CO2(g) is thermodynamically unstable with respect to the carbon in calcium...
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1. Calcium carbonate undergoes thermal decomposition CaCO3(s) ⇌ CaO(s) + CO2(g) at high temperatures. The equilibrium constant for the reaction is 0.0120 at 900 K. Calculate the partial pressure of carbon dioxide, CO2, when calcium carbonate, CaCO3, is heated at 900 K. 2. Calculate the standard cell potential for the reaction Zn(s)|Zn^2+(aq)||MnO^4-(aq), Mn^2+(aq), H+(aq)|Pt(s) 3. The standard reaction Gibbs energy for the electrochemical reaction Cr2O7^2- + 2 Fe + 14 H+ → 2 Cr3+ + 2 Fe3+ 7 H2O is -793 kJ mol-1. Calculate the standard cell potential.
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