4. Draw structures corresponding to the following names: (a) 2,2-Dimethylpropanoyl chloride (c) 5,5-Dimethylhexanenitrile (e) trans-2-Methylcyclohexanecarboxamide (f) p-Methylbenzoic anhydride (b) N-Methylbenzamide (d) tert-Butyl butanoate

4. Draw structures corresponding to the following names: (a) 2,2-Dimethylpropanoyl chloride (c) 5,5-Dimethylhexanenitrile (e) trans-2-Methylcyclohexanecarboxamide (f) p-Methylbenzoic anhydride (b) N-Methylbenzamide (d) tert-Butyl butanoate

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter22: Reactions Of Benzene And Its Derivatives

Section: Chapter Questions

Problem 22.61P

See similar textbooks

Related questions

Q: 1. The molecular formula of an unknown compound A is C7H14. On ozonolysis, A gave two products B…

A: The given compound (A) has molecular formula C7H14 which suggest that A is an alkene as alkenes have…

Q: Although ibuprofen is sold as a racemic mixture, only the S enantiomer acts as an analgesic. In the…

A: Since in the tautomerization reaction, the double bonded O will first take the proton from the HA…

Q: The oxidation of 3-methylbutanal with potassium permanganate in an acid medium produces compound A…

Q: 3. Starting from ethanoic anhydride, suggest how you would prepare the following compounds. a)…

Q: The shrub ma huang (Section 5.4A) contains two biologically activestereoisomers—ephedrine and…

A: Since you have posted a question with multiple sub-parts we will solve the first three sub-parts for…

Q: When acetophenone, hydroxelamine hydrochloride, and sodium hydroxide are reacted to synthesize…

Q: (b) Give two suggestions of chemical modification of the below compound to make it more drug-like.…

Q: 3. Suggest three different tests including chemical reactions and spectroscopical studies to…

A: Tollen's Test: Tollens' reagent (Ag+, NH3, OH-) is a chemical reagent used to distinguish between…

Q: Phenacetin has the structure shown. Write an equation for its preparation, starting from 4-…

Q: Trimyristin is obtained from coconut oil and has the molecular formula C45H86O6. On being heated…

A: Given : Trimyristin. To find : Desired product from the reaction. Solution : As we know that,…

Q: 1. Based on the poster below: THE CHEMISTRY OF INSECT REPELLENTS COMMON COMPOUNDS IN INSECT…

A: As per our guidelines, I can answer only first question. Because you have posted multiple questions.…

Q: b) Compound G (C₂H₂O) is a carbonyl compound that will give a negative test towards Tollen's…

A: Given in following question a compound G C4H8O ia carbonyl compound this compound give a negative…

Q: Write the complete stepwise mechanism for the acid-catalyzed hydrolysis of the following amide to…

Q: Treatment of salicylaldehyde (2-hydroxybenzaldehyde) with bromine in glacial acetic acid at 0°C…

Q: Compound X is optically inactive and has the formulaC 16H 16Br 2. On treatment with strong base, X…

Q: Give the expected organic product when phenylacetic acid, PhCH2COOH, is treated with reagent…

A: When carboxylic acid reacts with sodium hydroxide there will be a formation of sodium salt of that…

Q: Explain how (NH2CH2CH2NH2)2C03* catalyses the hydrolysis of compound I. H,N

Q: Much of our understanding of conformational analysis has arisen from studies on the reactions of…

A: The steroidal moiety builds the concept of trans-diaxial ring opening of epoxy-cycloalkanes. The…

Q: 1. Write the structure of the aminal or hemiaminal intermediate and the imine product formed in the…

A: “Hey, since there are multiple questions posted, we will answer first question. If you want any…

Q: Following is a series of anorexics (appetite suppressants). As you study their structures, you will…

A: An anorexia is a drug which causes loss of appetite that leads to weight loss. There are a numerous…

Q: Explain the observation that attempted Fischer esterification of 2.4,6-trimethylbenzoic acid with…

A: The solution is given below -

Q: Reduction of an alkyl azide results in the formation of —-. A. an imine B. an oxime C. a tertiary…

A: Alkyl azide have general formula R-N3

Q: Vancomycin is an important antibiotic. It is isolated from the bacterium Streptomyces orientalis and…

Q: „CHO NH3 H2. Ni A -H20 60 °C, 90 atm CI

A: Since the N in NH3 is having lone pair electron and C attached to O in the benzene reactant is…

Q: The reaction of cyclohexanone (1) and N,N-dimethylamine (2) with (i) sodium triacetoxyborohydride…

A: This is an example of reductive amination reaction in which an aldehyde or ketone reacts with amine…

Q: Molecules of 6,6'-dinitrobiphenyl-2,2'-dicarboxylic acid have no tetrahedral chiral center, and yet…

A: Chirality is defined as carbon atom bonded to four different groups, which are optically active.…

Q: Interesterification of two mono-acid triacylclycerols gives, in principle, 8 different kinds of…

A: Please find your solution below : Transesterification reaction is the process of exchanging the…

Q: Compound X is optically inactive and has the formula C 16H 16Br 2. On treatment with strong base, X…

A: When alkyl halide is treated with a base, elimination reaction can occur. The elimination can either…

Q: Give the expected organic product when phenylacetic acid, PhCH2COOH, is treated with reagent…

Q: Give the expected organic product when phenylacetic acid, PhCH2COOH, is treated with reagent Q.)…

A: In the chemical reaction between acid and SOCl2, acid chloride (a carboxylic acid derivative) is…

Q: It is a component of nylon 66. a. Phthalic acid b. Lauric acid O c. Benzoic acid d. Adipic acid e.…

Q: Acid-catalyzed hydrolysis of HOCH2CH2C(CH3)2CN forms compound A (C6H10O2). A shows a strong peak in…

A: The formula for given compound is C6H10O2. The DBE for this compound is calculated in order to…

Q: Rank the following compounds in order of increasing basicity: 1.p-nitroaniline I p-aminobenzaldehyde…

Q: 2. a)What happens when Isoamyl Alcohol is allowed to heated with Acetic Acid in presence of…

A: (a)Isoamyl alcohol reacts with acetic acid in the presence of concentrated sulfuric acid and gives…

Q: Proline betaine is a putative osmoprotectant in plants and bacteria, helping to prevent dehydration…

A: Given compound:

Q: Phenacetin has the structure given below. Write an equation for its preparation starting from…

A: To write the reaction of: Preparation of Phenacetin from 4-ethoxyaniline.

Q: (a). Benzphetamine is a habit-forming diet pill sold under the trade name Didrex. It is prescribed…

A: Stereogenic carbon has 4 different atoms or groups attached to it Hoffman elimination gives less…

Q: This molecule, N-methylcarbazole, absorbs light strongly at 330 nm and exhibits strong fluorescent…

Q: H,N-NH,

Q: b. Propose an electron pushing mechanism for the cyclization of the amide intermediate to…

A: The solution is given below -

Q: A chiral amine A having the R conguration undergoes Hofmann elimination to form an alkene B as the…

A: The ozonolysis of an alkene using reductive work up cleaves double bond to form two aldehyde or two…

Q: a O of d y 3. Suggest convenient methods of preparation of each of the following compounds from…

A: Concept behind synthesis of above four compound a) 1-indanone synthesis from dihydrocinnamic acid…

Q: Interesterification of two mono-acid triacylclycerols gives, in principle, 8 different kinds of…

Concept explainers

Aldehydes and Ketones

Aldehydes and ketones are organic compounds that have a carbonyl group, C = O, as their functional group. They both differ in the placement of this carbonyl group in their structures.

Question

4G. 4G
7:41 PM
27
4. Draw structures corresponding to the following names:
(a) 2,2-Dimethylpropanoyl chloride
(c) 5,5-Dimethylhexanenitrile
(e) trans-2-Methylcyclohexanecarboxamide (f p-Methylbenzoic anhydride
(b) N-Methylbenzamide
(d) tert-Butyl butanoate

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Compound A is a derivative of the carbohydrate perosamine, which is found in the antibiotic perimycin. When A is treated with acetic anhydride in methanol, a monoacyl derivative B (C9H17NO5) is obtained in 73% yield. What is the structure of compound B?
γ-Butyrolactone (C4H6O2, GBL) is a biologically inactive compound that is converted to the biologically active recreational drug GHB (Section 19.5) by a lactonase enzyme in the body. Since γ-butyrolactone is more fat soluble than GHB, it is more readily absorbed by tissues and thus produces a faster onset of physiological symptoms. γ-Butyrolactone shows an absorption in its IR spectrum at 1770 cm−1 and the following 1H NMR spectral data: 2.28 (multiplet, 2 H), 2.48 (triplet, 2 H), and 4.35 (triplet, 2 H) ppm. What is the structure of γ-butyrolactone?
Which is the stronger base: N-methylaniline (C6H5NHCH3) or benzylamine (C6H5CH2NH2). Explain your reasoning, supporting it with appropriate resonance contributors.
When N-bromosuccinimide is added to hex-1-ene in CCl4 and a sunlamp is shone on themixture, three products result.(a) Give the structures of these three products
(a) Give a plausible explanation for each one of the following :(i) There are two – NH2 groups in semicarbazide. However, only one such group is involved in the formation of semicarbazones.(ii) Cyclohexanone forms cyanohydrin in good yield but 2, 4, 6-trimethylcyclohexanone does not.(b) An organic compound with molecular formula C9H10O forms 2, 4, – DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro’s reaction. On vigorous oxidation it gives 1, 2-benzene-di- carboxylic acid. Identify the compound.
Compounds A, B, and C have the same molecular formula C4H8. They all react wotu H2/PtO2 to give the same compound. The reaction of A or B with H2O/H2SO4 or with BH3-THF, followed by treatment with a basic solution of hydrogen peroxide, gives the same compound, namely D. The reaction of C with H2O/H2SO4 also gives D. However, the reaction of C with BH3-THF, followed by HO-, H2O2 gives a new compound, E. Provide the identity of A, B, C, D, and E along with explanations of reactivity.
A solution of acetone [(CH3)2C=O] in ethanol (CH3CH2OH) in the presence of a trace of acid was allowed to stand for several days, and a new compound of molecular formula C7H16O2 was formed. The IR spectrum showed only one major peak in the functional group region around 3000 cm−1, and the 1H NMR spectrum is given here. What is the structure of the product?
In an aqueous solution containing sodium bicarbonate, aniline reacts quickly withbromine to give 2,4,6-tribromoaniline. Nitration of aniline requires very strong conditions,however, and the yields (mostly m-nitroaniline) are poor.(a) What conditions are used for nitration, and what form of aniline is present under theseconditions?
Compound A, C8H10O, has the IR and 1H NMR spectra shown. Propose a structure consistent with the observed spectra, and label each peak in the NMR spectrum. Note that the absorption at 5.5 î disappears when D2O is added.
The analgesic acetaminophen is synthesized by treating 4-aminophenol with one equivalent of acetic anhydride. Complete the equation for the formation of acetaminophen. a. Acetaminophen: b. Additional Product pls add the name for both, thanks!
Identify the structures of D and E, isomers of molecular formulaC6H12O2, from their IR and 1H NMR data. Signals at 1.35 and 1.60 ppm inthe 1H NMR spectrum of D and 1.90 ppm in the 1H NMR spectrum of Eare multiplets.
Phenacetin is an analgesic compound having molecular formula C10H13NO2. Once a common component in over-thecounter pain relievers such as APC (aspirin, phenacetin, caffeine), phenacetin is no longer used because of its liver toxicity. Deduce the structure of phenacetin from its 1H NMR and IR spectra.