4. Phosphoric acid is a triprotic weak acid with chemical formula H3PO4. Atomic masses of H, O, and Pare 1, 16, 30.97, respectively. (I ppm = Img/L) (20/100)i.Calculate the molar concentration of a 5 ppm solution of phosphoric acid.ii.Calculate the equivalent weight of phosphoric acid?ii.What is the normal concentration of the phosphoric acid in part (a)?iv.Calculate the alkalinity in "meq/L" for this phosphoric acid solution after adjusting solution pHto 12, where the dominant forms of phosphoric acid ions are HPO?- and PO- each amountingto 50% of the total phosphorous in the system, with negligible fractions of H3PO, and H2PO,.

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Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter15: Additional Aqueous Equilibria

Section: Chapter Questions

Problem 124QRT

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Consider the following six beakers. All have 100 mL of aqueous 0.1 M solutions of the following compounds: beaker A has HI beaker B has HNO2 beaker C has NaOH beaker D has Ba(OH)2 beaker E has NH4Cl beaker F has C2H5NH2 Answer the questions below, using LT (for is less than), GT (for is greater than), EQ (for is equal to), or MI (for more Information required). (a) The pH in beaker A the pH in beaker B. (b) The pH in beaker C the pH in beaker D. (c) The % ionization in beaker A the % ionization in beaker C. (d) The pH in beaker B the pH in beaker E. (e) The pH in beaker E the pH in beaker F. (f) The pH in beaker C the pH in beaker F.
A solution is prepared from 0.150 mol of formic acid and enough water to make 0.425 L of solution. a Determine the concentrations of H3O+ and HCOO in this solution. b Determine the H3O+ concentration that would be necessary to decrease the HCOO concentration above by a factor of 10. How many milliliters of 2.00 M HCl would be required to produce this solution? Consider that the solution was made by combining the HCl, the HCOOH, and enough water to make 0.425 L of solution. c Qualitatively, how can you account for the differences in the percentage dissociation of formic acid in parts a and b of this problem?
. Choose the answer that best completes the following statement and defend your answer. When 100.0 mL of water is added to 100.0 mI of 1.00 M HCI. a. the pH decreases because the solution is diluted. b. the pH does not change because water is neutral. c. the pH is doubled because the volume is now doubled. d the pH increases because the concentration of H decreases e. the solution is completely neutralized.
For each of the following cases, decide whether the pH is less than 7, equal to 7, or greater than 7. (a) Equal volumes of 0.10 M acetic acid, CH3CO2H, and 0.10 M KOH are mixed. (b) 25 mL of 0.015 M NH3 is mixed with 12 mL of 0.015 M HCl. (c) 150 mL of 0.20 M HNO3, is mixed with 75 mL of 0.40 M NaOH. (d) 25 mL of 0.45 M H2SO4 is mixed with 25 mL of 0.90 M NaOH.
Calculate the pH of each of the following solutions. (a) 10.0 mL of 0.300 M hydrofluoric acid plus 30.0 mL of 0.100 M sodium hydroxide (b) 100.0 mL of 0.250 M ammonia plus 50.0 mL of 0.100 M hydrochloric acid (c) 25.0 mL of 0.200 M sulfuric acid plus 50.0 mL of 0.400 M sodium hydroxide
What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?
A solution is tested for pH and conductivity as pictured below: The solution contains one of the following substances: HCl. NaOH, NH4Cl. HCN, NH3, HF, or NaCN. If the solute concentration is about 1.0 M, what is the identity of the solute?
Composition diagrams, commonly known as alpha plots, are often used to visualize the species in a solution of an acid or base as the pH is varied. The diagram for 0.100 M acetic acid is shown here. The plot shows how the fraction [alpha ()] of acetic acid in solution, =[CH3CO2H][CH3CO2H]+[CH3CO2] changes as the pH increases (blue curve). (The red curve shows how the fraction of acetate ion, CH3CO2, changes as the pH increases.) Alpha plots are another way of viewing the relative concentrations of acetic acid and acetate ion as a strong base is added to a solution of acetic acid in the course of a titration. (a) Explain why the fraction of acetic acid declines and that of acetate ion increases as the pH increases. (b) Which species predominates at a pH of 4, acetic acid or acetate ion? What is the situation at a pH of 6? (c) Consider the point where the two lines cross. The fraction of acetic acid in the solution is 0.5, and so is that of acetate ion. That is, the solution is half acid and half conjugate base; their concentrations are equal. At this point, the graph shows the pH is 4.74. Explain why the pH at this point is 4 74.
A solution of an unknown weak base (nonelectrolyte) at 25C has an osmotic pressure of 1.287 atm and a pH of 8.94. (Assume that, in the equation for [Chapter 101,i1.) What is Ka for its conjugate acid?
The active ingredient formed by aspirin in the body is salicylic acid, C6H4OH(CO2H). The carboxyl group. (-CO2H) acts as a weak acid. The phenol group (an OH group bonded to an aromatic ring) also acts as an acid but a much weaker acid. List, in order of descending concentration, all of the ionic and molecular species present in a 0.001-M aqueous solution of C6H4OH(CO2H).
Explain why a sample of pure water at 40 C is neutral even though [H3O+]=1.7107M . Kw is 2.91014 at 40 C.
What is the freezing point of 0.92 M aqueous acetic acid? The density of this solution is 1.008 g/cm3.

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