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4. The following have to do with rotational partition functions. a) What are the symmetry numbers o for the following molecules? i) "C"CI ii) "C*CI iii) triangular H3*

4. The following have to do with rotational partition functions. a) What are the symmetry numbers o for the following molecules? i) "C"CI ii) "C*CI iii) triangular H3*

Physical Chemistry
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.23E: Which of the following molecules should have pure rotational spectra? a Deuterium, D2 D is 2H b...
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4. The following have to do with rotational partition functions. a) What are the symmetry numbers o for the following molecules? i) *CI"CI ii) *CI*CI iii) triangular H;* iv) All isomers of C;H;F2 v) CH;CI vi) benzene b) Assume at = 10 the high temperature limit is reached. At what temperature does the high %3D temperature limit become valid for: i) DBr (B = 4.24 cm') ii) F"CI (B = 0.516 cm') iii) Csl (B = 0.236 cm') c) Obtain Jmax and for the temperatures obtained in part b) and at 500 K.
Transcribed Image Text:4. The following have to do with rotational partition functions. a) What are the symmetry numbers o for the following molecules? i) *CI"CI ii) *CI*CI iii) triangular H;* iv) All isomers of C;H;F2 v) CH;CI vi) benzene b) Assume at = 10 the high temperature limit is reached. At what temperature does the high %3D temperature limit become valid for: i) DBr (B = 4.24 cm') ii) F"CI (B = 0.516 cm') iii) Csl (B = 0.236 cm') c) Obtain Jmax and for the temperatures obtained in part b) and at 500 K.
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