4. Write the principal products of the reactions of the following compound with excess of the following reagents: c=CH d) A mixture of osmic acid and hydrogen peroxide e) Hot and concentrated potassium permanganate f) Peroxyacetic acid in acidic water

4. Write the principal products of the reactions of the following compound with excess of the following reagents: c=CH d) A mixture of osmic acid and hydrogen peroxide e) Hot and concentrated potassium permanganate f) Peroxyacetic acid in acidic water

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter16: Aldehydes And Ketones

Section: Chapter Questions

Problem 16.45P: The following bicyclic ketone has two -carbons and three -hydrogens. When this molecule is treated...

See similar textbooks

Related questions

Q: HO CH2CH2NH2 The compound is an alkaloid found in ripe cheese. Show how you would synthesize it from…

A: In this question, we have to synthesis the given compound from the starting material benzene and…

Q: The following compound is treated with excess K2Cr2O7. Provide the name of the product that would…

A: K2Cr2O7 is an oxidising agent. It oxidised secondary alcohol into ketone.

Q: Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.(a)…

A: Since we only answer up to 3 sub-parts, we’ll answer the first 3. Please resubmit the question and…

Q: What is the products you expect from oxidation of 2-Hexanol with CrO3 and H3O+?

A: Since the reactant 2-hexanol is a secondary alcohol. Hence it can be oxidised upto ketone only…

Q: What is the major organic product obtained from the following reaction?

A: Heating of carboxylic acid may undergo decarboxylation (i.e., release of CO2 ). So, here we have to…

Q: Which of the following set of reagents will yield a vicinal diol when reacted with an alkene? a…

A: ->Vicinal diol is Compound in which -OH group attached at adjacent carbons.

Q: 3. 'Please provide the products for the following reactions by writing the structures of the…

A: The above given reactions are pericyclic reactions or [2+4] cyclo addition. These reactions were…

Q: The biosynthesis of lanosterol from squalene has intrigued chemistssince its discovery. It is now…

A: a. The first step is the protonation of hydroxyl group. In the next step, elimination of water…

Q: Consider the following transformation. Which reagent would give you the indicated product s. NalO4…

Q: HO .CH2CH2NH2 The compound is an alkaloid found in ripe cheese. Show how you would synthesize it…

A: In this question, we have to synthesis the given organic compound from the starting material benzene…

Q: What products are formed when the following compounds react with CH3MgBr, followed by the addition…

Q: Which of the following is the condensation product formed from two moles of Acetophenone (C6H5COCH3)…

Q: to Br B A

Q: Propanal (CH3CH½CHO) is used in the pharmaceutical industry to make essential ingredients, organic…

A: Rate expression is totally dependent upon reactants.

Q: Compound X has molecular formula C7H14. Hydrogenation of compound X produces 2,4-dimethylpentane.…

Q: What is the product resulted due to the reaction of 2-hydroxy-3-methoxybenzaldehyde with ethyl…

A: We have to give the products of the given reactions under basic condition.

Q: 3.Synthsize the following compounds from the starting materials and necessary chemical reagents. а.…

A: Synthsize of following materials

Q: Suggest reagents for each of the following reactions

A: a)The reagents needed for the conversion of acetic anhydride to 2 mol of acetic acid are Pyridine…

Q: . identify the structure of A and B in the following synthetic scheme: Write out complete reactions…

A: By observing the nature of the reagents used, we can expect ketone and imine as products…

Q: CH;CH3OH HCI CO2H

A: Given : Reaction of butanoic acid with ethanol in presence of acid. To find : Product of the…

Q: он D From the structures above, select the compound(s) with the following properties: a) The…

A: (a) An alkene may form alcohol but does not yield ketone in the presence of acidified water. Hence,…

Q: Identify the reagents for each of the following reactions:

Q: 5) Draw the structure, showing the stereochemistry, of the cyclic products 19 and 20, and the…

Q: 3. Which of the following alcohols could not be made selectively by hydroboration/ oxidation of an…

A: The addition in the hydroboration reaction takes place with the help of Morkonikovs rule. The rule…

Q: Propose a mechanism for base-promoted conversion of the proposed intermediate to sodium…

A: Conversion of an alpha-haloketone to a carboxylic acid promoted by a base, known as Favorskii…

Q: When butan-2-ol undergoes acid catalysed dehydration reaction, a mixture of products, B and C, are…

A: Organic reaction mechanisms

Q: Reaction B. 1. B2H6 2. H2О2 (аq) 3M NaOH

Q: 3.3 8 Give the reaction mechanism and name the products for the reaction of 2-bromobutane with a hot…

Q: The product of the reaction of methyl cyclopentene with iodine monochloride is: CH, CH O 1. Achiral…

A: The reagent iodine monochloride because of electronegativity differences, the iodine act as an…

Q: Predict the products from reaction of 5-decyne with the following reagents: a) H2, Lindlar catalyst…

A: To find: the reaction of 5-decyne with the following reagents: a) H2 Lindlar catalyst b) Li in NH3…

Q: What product would you obtain by hydration of oct-4-yne?

A: Alkynes are the unsaturated hydrocarbons that have Carbon Carbon triple bind in the molecules. The…

Q: What product (including stereochemistry) is formed in each of the attachedintramolecular reactions?

A: Given reaction,

Q: Choose the most appropriate reagent(s) to selectively reduce the ketone functional group to an…

A: ->NaBH4 is reducing agent which can reduce ketone to alcohol and it is unable to reduce ester…

Q: OH CH₂CNHCH3 CH3 C d OH CHCHNHCH₂ CH3 Ephedrine can be synthesized via reductive amination plus…

Q: 3. Identify the products that will be formed when 2-heptyne reacts with each of the following…

Q: Identify A, B, and C, intermediates in the synthesis of the five-membered ring called an α-…

A: In the synthesis of the five-membered ring alpha-methylene-gamma-butyrolactone , the 3 intermediates…

Q: Devise a synthesis of each of the following compounds. Besidesinorganic reagents, you may use…

A: Given compound:

Q: 4 1. OH III. CH₂ Which of the following compounds is the expected product from the acid- catalyzed…

Q: In 1887, the Russian chemist Sergei Reformatsky at the University of Kiev dis- covered that…

A: Reformatsky reaction is type of organic reaction in which the condensation of an aldehyde or…

Q: (с) он

Q: 1-hexyne is reacted with lithium, then 1-bromopropane. The product of this reaction is then reduced…

Q: Provide the structure of the major organic product in the following reaction. CN A) B) CN CN CN D)…

Q: is

A: According to the question, we need to determine the major product of the organic reaction.

Q: CI Reaction 1 Reaction 2 ? NO2 ?

A: Which one of the following is correct

Q: cyclohexanone 0

A: Cyclohexanone is a cyclic ketone. NaBH4is a reducing agent used in chemical reaction.

Q: What is the major organic product to the following reaction with LIAIH, followed b acid hydrolysis?…

Q: Cyclohexanone can be effectively oxidized to adipic acid by treatment with which two of the…

Q: 4. Draw the structure of product, substrate or condition in the following reactions (should clearly…

A: Given are organic reactions.

Question

Please be clear in your writing

4. Write the principal products of the reactions of the following
compound with excess of the following reagents:
c=CH
d) A mixture of osmic acid and hydrogen peroxide
e) Hot and concentrated potassium permanganate
f) Peroxyacetic acid in acidic water

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Selection Rules for Pericyclic Reactions

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

An inexperienced graduate student treated dec-5-ene with borane in THF, placed the flask in a refrigerator, and left for aparty. When he returned from the party, he discovered that the refrigerator was broken and that it had gotten quite warminside. Although all the THF had evaporated from the flask, he treated the residue with basic hydrogen peroxide. Tohis surprise, he recovered a fair yield of decan-1-ol. Use a mechanism to show how this reaction might have occurred.(Hint: The addition of BH3 is reversible.)
Introduce the reaction and structure of the expected products (indicate the main product, when possible) for a reaction of 3-ethyl-5-methyl-hex-2-ene with the following reagents: (a) Br2, CH2Cl2 (b) H2O , Diluted H2SO4.
How many distinct alkene products are possible when the alkyl iodide below undergoes E2 elimination?
The following bicyclic ketone has two -carbons and three -hydrogens. When this molecule is treated with D2O in the presence of an acid catalyst, only two of the three -hydrogens exchange with deuterium. The -hydrogen at the bridgehead does not exchange. How do you account for the fact that two -hydrogens do exchange but the third does not? You will find it helpful to build models of the enols by which exchange of -hydrogens occurs.
Please give a detailed stepwise mechanism for the following reactions. All arrows, charges, and intermediates must be shown.
Complete the reaction schemes below providing the products of the reaction schemes below.
Predict the product of the following reaction and classify the reaction Pb+FeSO4---> PbSO4+ ______
Which of the following is a substrate product when benzene is first treated with Cl2 and FeCl3, and THEN treated (in a second step) with HNO3 and H2SO4?
One possible way of determining the identity of an alkene, is to let itundergo an oxidative cleavage reaction in the presence of hot basicpotassium permanganate. You are given two containers said to containdifferent alkenes. Container A is marked as cis / trans‐2‐butene andcontainer B as 2‐methyl‐1‐butene. Explain by referring to the formation ofproducts, how you would verify the identity of the alkenes.
Which products are obtained by the following reactions (a) and (b)? Specify the expected main product, if several products can be formed.
Give the major organic product(s) for each step in the following reactions (g,h,i,j)
If our starting material provided in the image were to react with CH(OMe)3 in DCM (solvent) and the use of Bi(OTf)3 (catalyst), propose a reasonable mechanism for the formation of dimethyl acetals.