5) Construct the orbital correlation diagram for hexatriene-cyclohexadiene interconversion, to what extend this obeys the Woodward-Hoffmann rules? 6) Using the Woodward-Hoffmann rules, predict the stereochemistry of each reaction a. a [6 + 4] thearmal cycloaddition b. photochemical electrocyclic ring closure of 1,3,5,7,9-decapentaene c. a [1 + 3] photochemical sigmatropic rearrangement d. photochemical ring opening of 1,3,5-cyclooctatriene
5) Construct the orbital correlation diagram for hexatriene-cyclohexadiene interconversion, to what extend this obeys the Woodward-Hoffmann rules? 6) Using the Woodward-Hoffmann rules, predict the stereochemistry of each reaction a. a [6 + 4] thearmal cycloaddition b. photochemical electrocyclic ring closure of 1,3,5,7,9-decapentaene c. a [1 + 3] photochemical sigmatropic rearrangement d. photochemical ring opening of 1,3,5-cyclooctatriene
Chapter14: Conjugated Compounds And Ultraviolet Spectroscopy
Section14.SE: Something Extra
Problem 38AP
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