Using the Woodward–Hoffmann rules, predict the stereochemistry of eachreaction.a. a [6 + 4] thermal cycloadditionb. photochemical electrocyclic ring closure of deca-1,3,5,7,9-pentaenec. a [4 + 4] photochemical cycloadditiond. a thermal [5,5] sigmatropic rearrangement
Using the Woodward–Hoffmann rules, predict the stereochemistry of eachreaction.a. a [6 + 4] thermal cycloadditionb. photochemical electrocyclic ring closure of deca-1,3,5,7,9-pentaenec. a [4 + 4] photochemical cycloadditiond. a thermal [5,5] sigmatropic rearrangement
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 33AP
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Using the Woodward–Hoffmann rules, predict the stereochemistry of each
reaction.
a. a [6 + 4] thermal cycloaddition
b. photochemical electrocyclic ring closure of deca-1,3,5,7,9-pentaene
c. a [4 + 4] photochemical cycloaddition
d. a thermal [5,5] sigmatropic rearrangement
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