5 Isopropylbenzene (C9H12) is commercially produced by Friedel–Crafts alkylation of compound H with 1-chloropropane in the presence of anhydrous aluminium chloride as a catalyst. CoH12 can be oxidized with strong oxidizing agent to form compound J. a) Draw the structure of H. b) Write the chemical reaction of isopropylbenzene to form compound J. c) Show the mechanism for the formation of isopropylbenzene (C,H12) from compound H.

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5
Isopropylbenzene (C9H12) is commercially produced by Friedel–Crafts alkylation of
compound H with 1-chloropropane in the presence of anhydrous aluminium chloride as a
catalyst. CyH12 can be oxidized with strong oxidizing agent to form compound J.
a)
Draw the structure of H.
b)
Write the chemical reaction of isopropylbenzene to form compound J.
c)
Show the mechanism for the formation of isopropylbenzene (C,H12) from
compound H.
C,H¬B1+ OH¯→ C,H¬OH + NaBr
The rate equation for the hydrolysis of C3H,Br with sodium hydroxide is:
rate = k [C3H»Br] [OH ¯]
a)
Draw the structural formula of C3H¬Br. Explain your answer.
b)
State and show the mechanism of the reaction above.
An alkyl halide E, C5H11B undergoes hydrolysis to form an alcohol F,
CSH120. Alcohol F becomes cloudy immediately when reacted with a Lucas reagent.
c)
(i)
(ii)
Deduce the structures of E and F.
State the type of reaction and propose the mechanism for the conversion of E to F.
d)
Draw the structure of the product formed when 2-bromopropane reacts with the following
reagents respectively,
(i)
potassium cyanide
(ii)
ethoxide ion
Transcribed Image Text:5 Isopropylbenzene (C9H12) is commercially produced by Friedel–Crafts alkylation of compound H with 1-chloropropane in the presence of anhydrous aluminium chloride as a catalyst. CyH12 can be oxidized with strong oxidizing agent to form compound J. a) Draw the structure of H. b) Write the chemical reaction of isopropylbenzene to form compound J. c) Show the mechanism for the formation of isopropylbenzene (C,H12) from compound H. C,H¬B1+ OH¯→ C,H¬OH + NaBr The rate equation for the hydrolysis of C3H,Br with sodium hydroxide is: rate = k [C3H»Br] [OH ¯] a) Draw the structural formula of C3H¬Br. Explain your answer. b) State and show the mechanism of the reaction above. An alkyl halide E, C5H11B undergoes hydrolysis to form an alcohol F, CSH120. Alcohol F becomes cloudy immediately when reacted with a Lucas reagent. c) (i) (ii) Deduce the structures of E and F. State the type of reaction and propose the mechanism for the conversion of E to F. d) Draw the structure of the product formed when 2-bromopropane reacts with the following reagents respectively, (i) potassium cyanide (ii) ethoxide ion
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