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- Does cis- or trans-1-bromo-4-tert-butylcylohexane react faster in an E2reaction?2. In not more than three (3) sentences, explain why terminal alkynes are acidic.3. What impurities are removed when acetylene gas is made to pass through an acidifiedsolution of CuSO4?4. Explain the difference in the rate of free radical bromination reactions of toluene and cyclohexane.Which reacts faster in an E2 elimination, cis-or-trans1-bromo-3-tert-butylcyclohexane
- True or false? 2-bromo-2-methylpropane undergoes SN1 rather than SN2 because the nucleophile experiences steric hindrance, and a stable carbocation can be formed. When hydroxide ion reacts with 1-chloropropane the main product is 1-propanol.6. Identify the best reagent(s) for this reaction. (see attached screenshot). a. H2SO4, HgSO4, H2O b. 1. Disiamylborane, 2. HO–, H2O2 c. K2Cr2O7, H+ d. NaOCl e. H2, PdExplain why the trifluoromethane sulfonate (TfO-) ion is a better leaving group than the methanesulfonate (MsO-) ion.
- Rank the nucleophiles in each group in order of increasing nucleophilicity.a. -OH, -NH2, H2Ob. -OH, Br-, F- (polar aprotic solvent)c. H2O, -OH, CH3CO2-For problem 8.17, all of the reactions will be SN2. For each reaction, identify and evaluate each nucleophile (strong? weak? Strong or weak as a base?) Also, evaluate each solvent as polar protic or polar aprotic. I recommend drawing the structure of each solvent. (g) Sodium methanethiolate (NaSCH3) in ethanolWhat reagents could I use to favour product 2-A over 2-B - explain?
- Consider the E1 reaction of 3-bromo-2-cyclohexyl-butane. How many elimination products are possible? Include (E)/(Z) isomers as separate products.Order the following sets from most reactive #1 to least reactive #42) Draw and name the organic compound found in every reaction. d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide f) Formation of Gilman reagent using isopropyl bromide g) Ozonolysis of 3,3-Dimethyloct-4-yne h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne j) Reaction of 3,4-Dimethylcyclodecyne with sodium amide