5. Classify the items in no. 4 according to (i) type of functional group and (ii) number of carbon atoms. (e.g. ketohexose)

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter12: Chirality
Section: Chapter Questions
Problem 11CTQ
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#4 Classify B D F H on what type of functional group and number of carbon atoms.

9.45
←
ACTIVITY
1. Identify whether the following objects are chiral or achiral.
nail
hammer
baseball cap
shoe
scissors
fork
foot
nose
Chapter 2 Acti...
2. Identify whether the circled carbon atom in each of the following molecules is a chiral
center. (Answer the items as chiral or achiral)
CH3-CH₂-OH
a.
b.
C. CH₂-CH-OH
CH3
e. CH,–CH,–NH,
a.
g. CH₂-CH-CH₂
NH₂
screwdriver
baseball glove
a.
pliers
spoon
hand
ear
C.
e.
3. Label the chiral carbon atom(s) with asterisk (*).
0
g.
a.
CH₂-CH-CH-CH-C-H
T LL L
OH OH OH OH
4. Classify the following as a D enantiomer or an L enantiomer.
CHO
HO-H
-H
HO-H
H-OH
H-OH
-ОН
CH₂OH
CH₂OH
C=0
HO-H
HO-H
CH₂OH
CH₂OH
T
c=0
H-OH
HO-H
H-OH
CH₂OH
СНО
H-OH
H-OH
H-OH
HO-H
CH₂OH
CH3-CH-OH
CI
d. CH3-CH₂-CH-OH
CH₁
£ CH-CH-NH,
CH3
h. CH₂-OH-NH₂
CI
CHO
H-LOH
CHU
H -OH
b.
CHO
b. HO-H
HO-H
HO-H
d.
f.
CH₂-CH-CH-CH-C-H
OH OH OH
h.
CH₂OH
CH₂OH
C=0
H-OH
H-OH
HO-H
CH₂OH
CHO
H-OH
HO-H
H-OH
НО
HO-H
CH₂OH
CHO
HO-H
5. Classify the items in no. 4 according to (i) type of functional group and (ii) number of
carbon atoms. (e.g. ketohexose)
H-OH
H-OH
CH₂OH
6. Characterize the members of each of the following pairs of structures as (i) enantiomers,
(ii) diastereomers or (iii) neither enantiomers nor diastereomers.
@
D.
CHU
H -OH
CHO
H-H
87
Transcribed Image Text:9.45 ← ACTIVITY 1. Identify whether the following objects are chiral or achiral. nail hammer baseball cap shoe scissors fork foot nose Chapter 2 Acti... 2. Identify whether the circled carbon atom in each of the following molecules is a chiral center. (Answer the items as chiral or achiral) CH3-CH₂-OH a. b. C. CH₂-CH-OH CH3 e. CH,–CH,–NH, a. g. CH₂-CH-CH₂ NH₂ screwdriver baseball glove a. pliers spoon hand ear C. e. 3. Label the chiral carbon atom(s) with asterisk (*). 0 g. a. CH₂-CH-CH-CH-C-H T LL L OH OH OH OH 4. Classify the following as a D enantiomer or an L enantiomer. CHO HO-H -H HO-H H-OH H-OH -ОН CH₂OH CH₂OH C=0 HO-H HO-H CH₂OH CH₂OH T c=0 H-OH HO-H H-OH CH₂OH СНО H-OH H-OH H-OH HO-H CH₂OH CH3-CH-OH CI d. CH3-CH₂-CH-OH CH₁ £ CH-CH-NH, CH3 h. CH₂-OH-NH₂ CI CHO H-LOH CHU H -OH b. CHO b. HO-H HO-H HO-H d. f. CH₂-CH-CH-CH-C-H OH OH OH h. CH₂OH CH₂OH C=0 H-OH H-OH HO-H CH₂OH CHO H-OH HO-H H-OH НО HO-H CH₂OH CHO HO-H 5. Classify the items in no. 4 according to (i) type of functional group and (ii) number of carbon atoms. (e.g. ketohexose) H-OH H-OH CH₂OH 6. Characterize the members of each of the following pairs of structures as (i) enantiomers, (ii) diastereomers or (iii) neither enantiomers nor diastereomers. @ D. CHU H -OH CHO H-H 87
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