5. Followed from the previous question, it was determined that K for the reaction at 25°C between CIO and H;Oz was 1.2 x 107. Calculate AG and Ecel from the given K. What is the implication of K having such an enormous value? Use Faraday constant, F=96485 C/mol.

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Chapter18: Introduction To Electrochemistry
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5. Followed from the previous question, it was determined that K for the reaction at
25°C between CIO and H2O2 was 1.2 x 10. Calculate AG° and E celi from the
given K. What is the implication of K having such an enormous value? Use Faraday
constant, F=96485 C/mol.
6. Calculate the Ecel value (non-standard state) at 298 K for the cell based on the reaction,
Fe"(ag) + Cu'(ag)– Fe"(aq) + Cu (ag),
when [Fe"]=[Cu'] - 2.56 x 10-3 M and [Fe2*]= [Cu*]-8.25 x 10 M.
Fe"(aq) + e - Fe2"(aq) E = 0.770 V
Cu"(aq) + e - Cu (ag) E = 0.153 V
RT
-In Q and Q=
nF
[FeTCu
Fe* ][Cu*]
Note: Use E= E-
Transcribed Image Text:5. Followed from the previous question, it was determined that K for the reaction at 25°C between CIO and H2O2 was 1.2 x 10. Calculate AG° and E celi from the given K. What is the implication of K having such an enormous value? Use Faraday constant, F=96485 C/mol. 6. Calculate the Ecel value (non-standard state) at 298 K for the cell based on the reaction, Fe"(ag) + Cu'(ag)– Fe"(aq) + Cu (ag), when [Fe"]=[Cu'] - 2.56 x 10-3 M and [Fe2*]= [Cu*]-8.25 x 10 M. Fe"(aq) + e - Fe2"(aq) E = 0.770 V Cu"(aq) + e - Cu (ag) E = 0.153 V RT -In Q and Q= nF [FeTCu Fe* ][Cu*] Note: Use E= E-
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