51. A 1.0 m solution of HCl in benzene has a freezing point of 0.4 °C. Is HCl an electrolyte in benzene? Explain. gler

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter13: Solutions And Their Behavior
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based on the question,how do we know benzene freeze ar 5.5C?how do we know Kf is 5.14C/m???I am confused . How does delta Tf decide if HCl whether or not a electrolyte in benzene?
51. A 1.0 m solution of HCl in benzene has a freezing point of 0.4 °C. Is HCl an electrolyte
benzene? Explain.
in
Solution
260i1?kelfing?
when dissoke in waler
No. Pure benzene freezes at 5.5 °C, and so the observed freezing point of this solution is
Mest
depressed by ATf=5.5 – 0.4=5.1 °C. The value computed, assuming no ionization of HCI, is
produe
(on
AT = (1.0 m)(5.14 °C/m)= 5.1 °C. Agreement of these values supports the assumption that HCI
is not ionized.
Transcribed Image Text:51. A 1.0 m solution of HCl in benzene has a freezing point of 0.4 °C. Is HCl an electrolyte benzene? Explain. in Solution 260i1?kelfing? when dissoke in waler No. Pure benzene freezes at 5.5 °C, and so the observed freezing point of this solution is Mest depressed by ATf=5.5 – 0.4=5.1 °C. The value computed, assuming no ionization of HCI, is produe (on AT = (1.0 m)(5.14 °C/m)= 5.1 °C. Agreement of these values supports the assumption that HCI is not ionized.
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