6) Dissolving 3.0 g of CaCl2(s) in 150.0 g of water in a calorimeter at 22.4 °C causes the temperature to rise to 25.8 °C. What is the approximate amount of heat involved in the dissolution, assuming the specific heat of the resulting solution is 4.18 J/g °C? Is the reaction exothermic or endothermic?

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Chapter6: Thermochemisty
Section: Chapter Questions
Problem 6.109QP: A 21.3-mL sample of 0.977 M NaOH is mixed with 29.5 mL of 0.918 M HCl in a coffee-cup calorimeter...
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6) Dissolving 3.0 g of CaCl2(s) in 150.0 g of water in a calorimeter at 22.4 °C causes the temperature to rise
to 25.8 °C. What is the approximate amount of heat involved in the dissolution, assuming the specific heat
of the resulting solution is 4.18 J/g °C? Is the reaction exothermic or endothermic?
7) A 100.0 mL sample of 0.300 M NaOH is mixed with a 100.0 mL sample of 0.300 M HNO3 in a coffee cup
calorimeter. If both solutions were initially at 35.00°C and the temperature of the resulting solution was
recorded as 37.00°C, determine the AH°rxn (in units of kJ/mol NaNO3) for the neutralization reaction
between aqueous NaOH and HNO3.
Assume:
1) that no heat is lost to the calorimeter or the surroundings
2) that the density and the heat capacity of the resulting solution are the same as water.
8) The addition of hydrochloric acid to a silver nitrate solution precipitates silver chloride according to the
reaction:
AGNO3(aq) + HCl(aq) → AgCl(s) + HNO3(aq)
you combine 50.0 mL of 0.100 M AGNO3 with 50.0 mL of 0.100 M HCI in a coffee-cup calorimeter,
the temperature changes from 23.40 °C to 24.21 °C. Calculate AHxn for the reaction as written. Use 1.00
g/mL as the density of the solution and C = 4.18 J/g °C as the specific heat capacity.
When
Transcribed Image Text:6) Dissolving 3.0 g of CaCl2(s) in 150.0 g of water in a calorimeter at 22.4 °C causes the temperature to rise to 25.8 °C. What is the approximate amount of heat involved in the dissolution, assuming the specific heat of the resulting solution is 4.18 J/g °C? Is the reaction exothermic or endothermic? 7) A 100.0 mL sample of 0.300 M NaOH is mixed with a 100.0 mL sample of 0.300 M HNO3 in a coffee cup calorimeter. If both solutions were initially at 35.00°C and the temperature of the resulting solution was recorded as 37.00°C, determine the AH°rxn (in units of kJ/mol NaNO3) for the neutralization reaction between aqueous NaOH and HNO3. Assume: 1) that no heat is lost to the calorimeter or the surroundings 2) that the density and the heat capacity of the resulting solution are the same as water. 8) The addition of hydrochloric acid to a silver nitrate solution precipitates silver chloride according to the reaction: AGNO3(aq) + HCl(aq) → AgCl(s) + HNO3(aq) you combine 50.0 mL of 0.100 M AGNO3 with 50.0 mL of 0.100 M HCI in a coffee-cup calorimeter, the temperature changes from 23.40 °C to 24.21 °C. Calculate AHxn for the reaction as written. Use 1.00 g/mL as the density of the solution and C = 4.18 J/g °C as the specific heat capacity. When
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