6. Complete the following reactions: 1. NaNH3 (CH,),CHCH,CH,C#CH 2. D,0 a. Lindlar's Catalyst H2 1. NANH2 CH3CH2C CH b. 2. PHCH2BR

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
Problem 15E
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6. Complete the following reactions:
1. NANH
(CH3),CHCH;CH;C=CH
2. D,0
a.
A
Lindlar's Catalyst
Ce
1. NANH2
CH3CH2C=CH-
b.
or
2. PHCH2BR
H2
Se
d.
Cor
2 eq. HBr
M
H,O, H;SO,
Doc
HESO,
Engl
BH
H2
H,O,, OH
Pd/BaSO,
Co
conc. KMNO.
Li
H;0
NH,
O,, -78 °C
H2
H;O,
Pd/C
Type here to search
DELL
F12
Transcribed Image Text:2/3 6. Complete the following reactions: 1. NANH (CH3),CHCH;CH;C=CH 2. D,0 a. A Lindlar's Catalyst Ce 1. NANH2 CH3CH2C=CH- b. or 2. PHCH2BR H2 Se d. Cor 2 eq. HBr M H,O, H;SO, Doc HESO, Engl BH H2 H,O,, OH Pd/BaSO, Co conc. KMNO. Li H;0 NH, O,, -78 °C H2 H;O, Pd/C Type here to search DELL F12
2 / 3
d.
e.
2 eq. HBr
H,O, H,SO4
H9SO4
BH,
H2
H,O2, OH
Pd/BaSO4
conc. KMNO4
Li
H2O
NH3
O3, -78 °C
H2
H,O,
Pd/C
HBr
D2
Pd/BaSO4, quinoline
-CEC-H
Ph C=C–Ph
f.
(1 equivalent)
g.
Br2 (1 eq)
h. H3C-C C-CH(CH3)2
P Type here to search
DELL
Transcribed Image Text:2 / 3 d. e. 2 eq. HBr H,O, H,SO4 H9SO4 BH, H2 H,O2, OH Pd/BaSO4 conc. KMNO4 Li H2O NH3 O3, -78 °C H2 H,O, Pd/C HBr D2 Pd/BaSO4, quinoline -CEC-H Ph C=C–Ph f. (1 equivalent) g. Br2 (1 eq) h. H3C-C C-CH(CH3)2 P Type here to search DELL
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