6. In class we went through a semi-empirical derivation of the i(t)-Eappi Curve expected in a voltammetry experiment involving a reversible redox reaction, 0.0592, -log- 0.0592, Flog mo. m (t) – i(t)) i(t) Eapol E mR Eq. 2-1 Show how to rearrange Eq. 2-1 to yield an expression to calculate the current i(t) for a particular Egppl value, i(1) = f(E appl ) -

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter22: Bulk Electrolysis: Electrogravimetry And Coulometry
Section: Chapter Questions
Problem 22.30QAP
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6. In class we went through a semi-empirical derivation of the i(t)-Eappl Curve expected in a voltammetry
experiment involving a reversible redox reaction,
0.0592,
mR
m(t) – i(t)
0.0592
Eappl =|E+
Flog-
mo
-log
n
Eq. 2-1
n
i(t)
Show how to rearrange Eq. 2-1 to yield an expression to calculate the current i(t) for a particular Egppl
value, i(t) = f(E appl ) -
Transcribed Image Text:6. In class we went through a semi-empirical derivation of the i(t)-Eappl Curve expected in a voltammetry experiment involving a reversible redox reaction, 0.0592, mR m(t) – i(t) 0.0592 Eappl =|E+ Flog- mo -log n Eq. 2-1 n i(t) Show how to rearrange Eq. 2-1 to yield an expression to calculate the current i(t) for a particular Egppl value, i(t) = f(E appl ) -
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