6.6 One hundred liters of methyl methacrylate containing 10.2 moles of an initiator (ty2 = 50 h) in solution is polymerized át 60°C. Calculate (a) the kinetic chain length in this polymerization and (b) the amount of polymer formed in the first 1 h of reaction. [Data: monomer density 0.94 g/cm; kp = 515 L mol s-l; k = 2.55x107 L mol-s-l; f= 0.3.] %3D

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.34P
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6.6 One hundred liters of methyl methacrylate containing 10.2 moles of an initiator (t1/2
= 50 h) in solution is polymerized åt 60°C. Calculate (a) the kinetic chain length in
this polymerization and (b) the amount of polymer formed in the first 1 h of reaction.
[Data: monomer density 0.94 g/cm; kp = 515 L mol- s-l; k, 2.55x107 L
mol-s-1; f= 0.3.]
[Ans. (a) 1397; (b) 70 kg]
%3D
Transcribed Image Text:6.6 One hundred liters of methyl methacrylate containing 10.2 moles of an initiator (t1/2 = 50 h) in solution is polymerized åt 60°C. Calculate (a) the kinetic chain length in this polymerization and (b) the amount of polymer formed in the first 1 h of reaction. [Data: monomer density 0.94 g/cm; kp = 515 L mol- s-l; k, 2.55x107 L mol-s-1; f= 0.3.] [Ans. (a) 1397; (b) 70 kg] %3D
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