7. Identify (draw the structure) of the missing reactant, reagent or major product in the following transformations ( ). S-S SH 18 NaOH/ H20 EtO. EtO. OH H.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
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Organic chemistry 

7. Identify (draw the structure) of the missing reactant, reagent or major product in
the following transformations (pE ).
S-S
SH
18
NaOH/ H20
EtO
EtO.
H.
Вз / THF
or
H2O2 / OH
far
heat
Br2 /H2O
H H
NaOH /H2O
CS Scanned with CamScanner
Transcribed Image Text:7. Identify (draw the structure) of the missing reactant, reagent or major product in the following transformations (pE ). S-S SH 18 NaOH/ H20 EtO EtO. H. Вз / THF or H2O2 / OH far heat Br2 /H2O H H NaOH /H2O CS Scanned with CamScanner
4. Explain the stereochemistry of the following reactions shown below of the
products B & C (OR).
1.
SO2CI /pyridine
HO H
1.SOCI/ether
2. CH30 Na/CH,OH
2. CH;O Na/CH,OH
(R)-
(S)-
(S)-
A
B
5. Provide a detailed mechanism for the following reaction. Draw the structures of
the products. Explain your answer S).
HI
A
B
6. Methylcyclopentanol on treatment with HBr gives 1-bromo-1-methylcyclopentane
as a major product. Show a detailed mechanism to explain your answer .
S).
CH3
H3C
Br
HBr
но-
-H2O
2-methylcyclopentanol
1-bromo-1-methylcyclopentane
CS Scanned with CamScanner
Transcribed Image Text:4. Explain the stereochemistry of the following reactions shown below of the products B & C (OR). 1. SO2CI /pyridine HO H 1.SOCI/ether 2. CH30 Na/CH,OH 2. CH;O Na/CH,OH (R)- (S)- (S)- A B 5. Provide a detailed mechanism for the following reaction. Draw the structures of the products. Explain your answer S). HI A B 6. Methylcyclopentanol on treatment with HBr gives 1-bromo-1-methylcyclopentane as a major product. Show a detailed mechanism to explain your answer . S). CH3 H3C Br HBr но- -H2O 2-methylcyclopentanol 1-bromo-1-methylcyclopentane CS Scanned with CamScanner
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